Metal–Organic Frameworks and Water: ‘From Old Enemies to Friends’?

Georges Mouchaham; Frédéric S. Cui; Farid Nouar; Vanessa Pimenta; Jong San Chang; Christian Serre

doi:10.1016/j.trechm.2020.09.004

Metal–Organic Frameworks and Water: ‘From Old Enemies to Friends’?

Georges Mouchaham (Corresponding author), Frédéric S. Cui, Farid Nouar, Vanessa Pimenta, Jong San Chang, Christian Serre

Research output: Contribution to journal › Review article › peer-review

51 Citations (Scopus)

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Abstract

Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hydrolytic stability. Since then, significant effort has been devoted to design robust MOFs, including their utilization for water-related applications to overcome relevant societal challenges. This short review provides guidelines on the key parameters that drive the assembly of hydrothermally stable MOFs together with the most relevant physicochemical features needed in their water-related applications. It also highlights some of the recent advances in MOF-water applications (based on water sorption or mediation and separation in the presence of water) as well as the most critical challenges to overcome.

Original language	English
Pages (from-to)	990-1003
Number of pages	14
Journal	Trends in Chemistry
Volume	2
Issue number	11
DOIs	https://doi.org/10.1016/j.trechm.2020.09.004
Publication status	Published - Nov 2020

Bibliographical note

Funding Information:
G.M., F.N., and C.S. acknowledge the CNRS, ENS, ESPCI, and PSL University for financial support. F.S.C. acknowledges funding from the EU’s H2020 Programme under MSCA grant agreement no. 754462.

Keywords

hydrolytic stability
metal–organic framework
MOF
sorption
water-based applications

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title = "Metal–Organic Frameworks and Water: {\textquoteleft}From Old Enemies to Friends{\textquoteright}?",

abstract = "Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hydrolytic stability. Since then, significant effort has been devoted to design robust MOFs, including their utilization for water-related applications to overcome relevant societal challenges. This short review provides guidelines on the key parameters that drive the assembly of hydrothermally stable MOFs together with the most relevant physicochemical features needed in their water-related applications. It also highlights some of the recent advances in MOF-water applications (based on water sorption or mediation and separation in the presence of water) as well as the most critical challenges to overcome.",

keywords = "hydrolytic stability, metal–organic framework, MOF, sorption, water-based applications",

author = "Georges Mouchaham and Cui, {Fr{\'e}d{\'e}ric S.} and Farid Nouar and Vanessa Pimenta and Chang, {Jong San} and Christian Serre",

note = "Funding Information: G.M., F.N., and C.S. acknowledge the CNRS, ENS, ESPCI, and PSL University for financial support. F.S.C. acknowledges funding from the EU{\textquoteright}s H2020 Programme under MSCA grant agreement no. 754462. ",

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language = "English",

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AU - Mouchaham, Georges

AU - Cui, Frédéric S.

AU - Nouar, Farid

AU - Pimenta, Vanessa

AU - Chang, Jong San

AU - Serre, Christian

N1 - Funding Information: G.M., F.N., and C.S. acknowledge the CNRS, ENS, ESPCI, and PSL University for financial support. F.S.C. acknowledges funding from the EU’s H2020 Programme under MSCA grant agreement no. 754462.

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N2 - Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hydrolytic stability. Since then, significant effort has been devoted to design robust MOFs, including their utilization for water-related applications to overcome relevant societal challenges. This short review provides guidelines on the key parameters that drive the assembly of hydrothermally stable MOFs together with the most relevant physicochemical features needed in their water-related applications. It also highlights some of the recent advances in MOF-water applications (based on water sorption or mediation and separation in the presence of water) as well as the most critical challenges to overcome.

AB - Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hydrolytic stability. Since then, significant effort has been devoted to design robust MOFs, including their utilization for water-related applications to overcome relevant societal challenges. This short review provides guidelines on the key parameters that drive the assembly of hydrothermally stable MOFs together with the most relevant physicochemical features needed in their water-related applications. It also highlights some of the recent advances in MOF-water applications (based on water sorption or mediation and separation in the presence of water) as well as the most critical challenges to overcome.

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KW - metal–organic framework

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KW - sorption

KW - water-based applications

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Metal–Organic Frameworks and Water: ‘From Old Enemies to Friends’?

Abstract

Bibliographical note

Keywords

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