TY - JOUR
T1 - Metallo-supramolecular materials based on amine-grafting onto polypentafluorostyrene
AU - Guerrero Sanchez - Ott, C.
AU - Ulbricht, C.
AU - Hoogenboom, R.
AU - Schubert, U.S.
PY - 2012
Y1 - 2012
N2 - The post-modification of polypentafluorostyrene via the selective substitution of the para- fluorine by amine-functionalized molecules represents a versatile method for the preparation of functional materials. This communication presents the extension of this synthetic approach towards metallosupramolecular materials. First, the incorporation of terpyridines as metallo-supramolecular binding motifs is demonstrated, which enables the formation of a supramolecular crosslinked gel upon the addition of Fe(II) ions. Second, the linkage of phosphorescent iridium(III) complexes is reported yielding a copolymer that combines the excellent photophysical properties of the iridium(III) complex and the good solubility and processability of the polymer
AB - The post-modification of polypentafluorostyrene via the selective substitution of the para- fluorine by amine-functionalized molecules represents a versatile method for the preparation of functional materials. This communication presents the extension of this synthetic approach towards metallosupramolecular materials. First, the incorporation of terpyridines as metallo-supramolecular binding motifs is demonstrated, which enables the formation of a supramolecular crosslinked gel upon the addition of Fe(II) ions. Second, the linkage of phosphorescent iridium(III) complexes is reported yielding a copolymer that combines the excellent photophysical properties of the iridium(III) complex and the good solubility and processability of the polymer
U2 - 10.1002/marc.201100769
DO - 10.1002/marc.201100769
M3 - Article
C2 - 22287489
SN - 1022-1336
VL - 33
SP - 556
EP - 561
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 6-7
ER -