TY - JOUR
T1 - Metallo-supramolecular diethylene glycol : water-soluble reversible polymers
AU - Schmatloch, S.
AU - Fernández González, M.
AU - Schubert, U.S.
PY - 2002
Y1 - 2002
N2 - Bis(2,2:6,2-terpyrid-4-yl) diethylene glycol was synthesized as a monomer unit and further utilized for polymerization with FeCl2 in order to form water-soluble coordination polymers. Viscosity measurements and film-forming properties indicate the formation of linear coordination polymers or larger ring structures. The terpyridine/iron(II) complexes are stable up to temperatures of 210 °C, but can be uncomplexed by the addition of an excess of a strong competitive ligand (HEDTA) under mild conditions.
AB - Bis(2,2:6,2-terpyrid-4-yl) diethylene glycol was synthesized as a monomer unit and further utilized for polymerization with FeCl2 in order to form water-soluble coordination polymers. Viscosity measurements and film-forming properties indicate the formation of linear coordination polymers or larger ring structures. The terpyridine/iron(II) complexes are stable up to temperatures of 210 °C, but can be uncomplexed by the addition of an excess of a strong competitive ligand (HEDTA) under mild conditions.
U2 - 10.1002/1521-3927(200211)23:16<957::AID-MARC957>3.0.CO;2-W
DO - 10.1002/1521-3927(200211)23:16<957::AID-MARC957>3.0.CO;2-W
M3 - Article
SN - 1022-1336
VL - 23
SP - 957
EP - 961
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 16
ER -