Metal complex containing one or more silsesquioxane ligands

M.F.H. Tol, van (Inventor), S.K.H. Thiele (Inventor), R. Duchateau (Inventor), H.C.L. Abbenhuis (Inventor), R.A. Santen, van (Inventor)

Research output: PatentPatent publication

65 Downloads (Pure)

Abstract

Metal complex containing one or more silsesquioxane ligands, having the formula Zy(MAxBq)b (I), wherein Z is a silsesquioxane according to the formula R7-lSi7O12YD1+l (II), M is a metal from groups 3-6 of the Periodic System of the Elements and the lanthanides, A is a monoanionic ligand bound to the metal, B is a pi-bound ligand, y represents the number of silsesquioxane ligands and is 1-10, b represents the number of metal groups and is 1-20, q is 0, 1 or 2, x is the number of substituents A bound to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bound to Si, Y is an atom from group 13 or 14 of the Periodic System of the Elements, D is a group, directly bound to Y or Si with one atom from group 15 or 16 of the Periodic System of the Elements and l determines the amount of substituents R and atoms D and is equal to 0, 1, 2 or 3.
Original languageEnglish
Publication statusPublished - 2002

Fingerprint

Coordination Complexes
Metals
Ligands
Time varying systems
Atoms
Lanthanoid Series Elements

Bibliographical note

Patent US2002065424 2002-05-30 ; US6441210(B1) ; EP0967229 1999-12-29 ; EP1088003 2001-04-04 ; WO0000519 2000-01-06 ; AU4658499 2001-01-17 ; JP2002519359T 2002-07-02

Cite this

Tol, van, M.F.H. (Inventor) ; Thiele, S.K.H. (Inventor) ; Duchateau, R. (Inventor) ; Abbenhuis, H.C.L. (Inventor) ; Santen, van, R.A. (Inventor). / Metal complex containing one or more silsesquioxane ligands.
@misc{f655dc7afe4d454ba4080a50ed8eac94,
title = "Metal complex containing one or more silsesquioxane ligands",
abstract = "Metal complex containing one or more silsesquioxane ligands, having the formula Zy(MAxBq)b (I), wherein Z is a silsesquioxane according to the formula R7-lSi7O12YD1+l (II), M is a metal from groups 3-6 of the Periodic System of the Elements and the lanthanides, A is a monoanionic ligand bound to the metal, B is a pi-bound ligand, y represents the number of silsesquioxane ligands and is 1-10, b represents the number of metal groups and is 1-20, q is 0, 1 or 2, x is the number of substituents A bound to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bound to Si, Y is an atom from group 13 or 14 of the Periodic System of the Elements, D is a group, directly bound to Y or Si with one atom from group 15 or 16 of the Periodic System of the Elements and l determines the amount of substituents R and atoms D and is equal to 0, 1, 2 or 3.",
author = "{Tol, van}, M.F.H. and S.K.H. Thiele and R. Duchateau and H.C.L. Abbenhuis and {Santen, van}, R.A.",
year = "2002",
language = "English",
type = "Patent",

}

Metal complex containing one or more silsesquioxane ligands. / Tol, van, M.F.H. (Inventor); Thiele, S.K.H. (Inventor); Duchateau, R. (Inventor); Abbenhuis, H.C.L. (Inventor); Santen, van, R.A. (Inventor).

Research output: PatentPatent publication

TY - PAT

T1 - Metal complex containing one or more silsesquioxane ligands

AU - Tol, van, M.F.H.

AU - Thiele, S.K.H.

AU - Duchateau, R.

AU - Abbenhuis, H.C.L.

AU - Santen, van, R.A.

N1 - Patent US2002065424 2002-05-30 ; US6441210(B1) ; EP0967229 1999-12-29 ; EP1088003 2001-04-04 ; WO0000519 2000-01-06 ; AU4658499 2001-01-17 ; JP2002519359T 2002-07-02

PY - 2002

Y1 - 2002

N2 - Metal complex containing one or more silsesquioxane ligands, having the formula Zy(MAxBq)b (I), wherein Z is a silsesquioxane according to the formula R7-lSi7O12YD1+l (II), M is a metal from groups 3-6 of the Periodic System of the Elements and the lanthanides, A is a monoanionic ligand bound to the metal, B is a pi-bound ligand, y represents the number of silsesquioxane ligands and is 1-10, b represents the number of metal groups and is 1-20, q is 0, 1 or 2, x is the number of substituents A bound to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bound to Si, Y is an atom from group 13 or 14 of the Periodic System of the Elements, D is a group, directly bound to Y or Si with one atom from group 15 or 16 of the Periodic System of the Elements and l determines the amount of substituents R and atoms D and is equal to 0, 1, 2 or 3.

AB - Metal complex containing one or more silsesquioxane ligands, having the formula Zy(MAxBq)b (I), wherein Z is a silsesquioxane according to the formula R7-lSi7O12YD1+l (II), M is a metal from groups 3-6 of the Periodic System of the Elements and the lanthanides, A is a monoanionic ligand bound to the metal, B is a pi-bound ligand, y represents the number of silsesquioxane ligands and is 1-10, b represents the number of metal groups and is 1-20, q is 0, 1 or 2, x is the number of substituents A bound to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bound to Si, Y is an atom from group 13 or 14 of the Periodic System of the Elements, D is a group, directly bound to Y or Si with one atom from group 15 or 16 of the Periodic System of the Elements and l determines the amount of substituents R and atoms D and is equal to 0, 1, 2 or 3.

M3 - Patent publication

ER -