Metal complex containing one or more silsesquioxane ligands

M.F.H. Tol, van (Inventor), S.K.H. Thiele (Inventor), R. Duchateau (Inventor), H.C.L. Abbenhuis (Inventor), R.A. Santen, van (Inventor)

Research output: PatentPatent publication

62 Downloads (Pure)

Abstract

Metal complex containing one or more silsesquioxane ligands having the formulaZy(MAx)b (I)wherein Z is a silsesquioxane ligand according to the formula(RSiO1.5)mOnBq (II)which is connected within one corner to one atom M or to two atoms M by one bridging oxygen atom, M is a metal from groups 3-10 of the Periodic System of the Elements and the lanthanides, A is a substituent bonded to the metal, y represents the number of silsesquioxane ligands and is 2-10, b represents the number of metal groups and is 2-20, x is the number of substituents A bonded to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bonded to each Si, m is an integer and is equal to 5-19, n is 1.5 or 3, B is a group bonded to an oxygen atom that has one bond to Si and q is 0, 1 or 2.
Original languageEnglish
Publication statusPublished - 2001

Bibliographical note

Patent US2001008926 2001-07-19 ; EP0967228 1999-12-29 ; EP1088001 2001-04-04 ; US6723806 (B2) ; WO0000518 2000-01-06 ; AU4659299 2000-01-17 ; JP2002519358T 2002-07-02

Fingerprint Dive into the research topics of 'Metal complex containing one or more silsesquioxane ligands'. Together they form a unique fingerprint.

Cite this