Metal complex containing one or more silsesquioxane ligands

M.F.H. Tol, van (Inventor), S.K.H. Thiele (Inventor), R. Duchateau (Inventor), H.C.L. Abbenhuis (Inventor), R.A. Santen, van (Inventor)

Research output: PatentPatent publication

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Abstract

Metal complex containing one or more silsesquioxane ligands having the formulaZy(MAx)b (I)wherein Z is a silsesquioxane ligand according to the formula(RSiO1.5)mOnBq (II)which is connected within one corner to one atom M or to two atoms M by one bridging oxygen atom, M is a metal from groups 3-10 of the Periodic System of the Elements and the lanthanides, A is a substituent bonded to the metal, y represents the number of silsesquioxane ligands and is 2-10, b represents the number of metal groups and is 2-20, x is the number of substituents A bonded to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bonded to each Si, m is an integer and is equal to 5-19, n is 1.5 or 3, B is a group bonded to an oxygen atom that has one bond to Si and q is 0, 1 or 2.
Original languageEnglish
Publication statusPublished - 2001

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Coordination Complexes
Metals
Ligands
Atoms
Oxygen
Lanthanoid Series Elements
Time varying systems

Bibliographical note

Patent US2001008926 2001-07-19 ; EP0967228 1999-12-29 ; EP1088001 2001-04-04 ; US6723806 (B2) ; WO0000518 2000-01-06 ; AU4659299 2000-01-17 ; JP2002519358T 2002-07-02

Cite this

Tol, van, M.F.H. (Inventor) ; Thiele, S.K.H. (Inventor) ; Duchateau, R. (Inventor) ; Abbenhuis, H.C.L. (Inventor) ; Santen, van, R.A. (Inventor). / Metal complex containing one or more silsesquioxane ligands.
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title = "Metal complex containing one or more silsesquioxane ligands",
abstract = "Metal complex containing one or more silsesquioxane ligands having the formulaZy(MAx)b (I)wherein Z is a silsesquioxane ligand according to the formula(RSiO1.5)mOnBq (II)which is connected within one corner to one atom M or to two atoms M by one bridging oxygen atom, M is a metal from groups 3-10 of the Periodic System of the Elements and the lanthanides, A is a substituent bonded to the metal, y represents the number of silsesquioxane ligands and is 2-10, b represents the number of metal groups and is 2-20, x is the number of substituents A bonded to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bonded to each Si, m is an integer and is equal to 5-19, n is 1.5 or 3, B is a group bonded to an oxygen atom that has one bond to Si and q is 0, 1 or 2.",
author = "{Tol, van}, M.F.H. and S.K.H. Thiele and R. Duchateau and H.C.L. Abbenhuis and {Santen, van}, R.A.",
year = "2001",
language = "English",
type = "Patent",

}

Metal complex containing one or more silsesquioxane ligands. / Tol, van, M.F.H. (Inventor); Thiele, S.K.H. (Inventor); Duchateau, R. (Inventor); Abbenhuis, H.C.L. (Inventor); Santen, van, R.A. (Inventor).

Research output: PatentPatent publication

TY - PAT

T1 - Metal complex containing one or more silsesquioxane ligands

AU - Tol, van, M.F.H.

AU - Thiele, S.K.H.

AU - Duchateau, R.

AU - Abbenhuis, H.C.L.

AU - Santen, van, R.A.

N1 - Patent US2001008926 2001-07-19 ; EP0967228 1999-12-29 ; EP1088001 2001-04-04 ; US6723806 (B2) ; WO0000518 2000-01-06 ; AU4659299 2000-01-17 ; JP2002519358T 2002-07-02

PY - 2001

Y1 - 2001

N2 - Metal complex containing one or more silsesquioxane ligands having the formulaZy(MAx)b (I)wherein Z is a silsesquioxane ligand according to the formula(RSiO1.5)mOnBq (II)which is connected within one corner to one atom M or to two atoms M by one bridging oxygen atom, M is a metal from groups 3-10 of the Periodic System of the Elements and the lanthanides, A is a substituent bonded to the metal, y represents the number of silsesquioxane ligands and is 2-10, b represents the number of metal groups and is 2-20, x is the number of substituents A bonded to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bonded to each Si, m is an integer and is equal to 5-19, n is 1.5 or 3, B is a group bonded to an oxygen atom that has one bond to Si and q is 0, 1 or 2.

AB - Metal complex containing one or more silsesquioxane ligands having the formulaZy(MAx)b (I)wherein Z is a silsesquioxane ligand according to the formula(RSiO1.5)mOnBq (II)which is connected within one corner to one atom M or to two atoms M by one bridging oxygen atom, M is a metal from groups 3-10 of the Periodic System of the Elements and the lanthanides, A is a substituent bonded to the metal, y represents the number of silsesquioxane ligands and is 2-10, b represents the number of metal groups and is 2-20, x is the number of substituents A bonded to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bonded to each Si, m is an integer and is equal to 5-19, n is 1.5 or 3, B is a group bonded to an oxygen atom that has one bond to Si and q is 0, 1 or 2.

M3 - Patent publication

ER -