Melt morphology of polystyrene-poly(ethylene oxide) metallo-supramolecular diblock copolymer

M. Al-Hussein, B.G.G. Lohmeijer, U.S. Schubert, W.H. Jeu, de

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Abstract

Using SAXS, the melt morphol. of a polystyrene-poly(ethylene oxide) metallo-supramol. diblock copolymer, which is prepd. by coupling terpyridine-terminated polyethylene oxide and terpyridine-terminated polystyrene with RuCl3, is studied, and the presence of the the metal-ligand complex (MLC) in the mol. chain leads to a different morphol. and drives the mol. to form spherical aggregates. The aggregate has a core radius of 1.5 nm surrounded by a polymer shell with an out radius of approx. 2.4 nm, and the size of the aggregate decreases with temp. and affects by the crystn. of the polyethylene oxide block. [on SciFinder (R)]
Original languageEnglish
Pages (from-to)9281-9284
JournalMacromolecules
Volume36
Issue number25
DOIs
Publication statusPublished - 2003

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Al-Hussein, M., Lohmeijer, B. G. G., Schubert, U. S., & Jeu, de, W. H. (2003). Melt morphology of polystyrene-poly(ethylene oxide) metallo-supramolecular diblock copolymer. Macromolecules, 36(25), 9281-9284. https://doi.org/10.1021/ma035183z