Mechanistic insight into the interaction between a titanium dioxide photocatalyst and Pd1 cocatalyst for improved photocatalytic performance

Ren Su, Nikolaos Dimitratos, Jinjia Liu, Emma Carter, Sultan Althahban, Xueqin Wang, Yanbin Shen, Stefan Wendt, Xiaodong Wen, J.W. Niemantsverdriet, Bo B. Iversen, Christopher J. Kiely, Graham J. Hutchings, Flemming Besenbacher

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    Understanding the cocatalyst/semiconductor interaction is of key importance for the design and synthesis of next generation photocatalytic materials for efficient hydrogen production and environmental cleanup applications. Here we investigate preformed Pd nanoparticles (NPs) supported on a series of anatase TiO2 having well-controlled but varying degrees of crystallinity and crystallite size, and explore their photocatalytic performance for H2 production and phenol decomposition. While tuning the anatase crystallite size significantly influences the photocatalytic performance, varying the TiO2 crystallinity shows a negligible effect. Interestingly, the optimum quantum efficiency (∼78%) for H2 evolution is achieved with anatase having medium crystallite size (∼16 nm), whereas for phenol decomposition, a promotional effect is only observed for anatase with larger crystallite sizes (>20 nm). Surface radical species and radical densities study reveal that the photogenerated charge carriers have been trapped at different sites depending on the crystallite size of anatase. While the excited electrons are only trapped in bulk lattice sites in small anatase (<16 nm), larger anatase particles provide extra surface sites for charge trapping, which benefit charge storage and transportation to Pd surface sites, leading to a more efficient utilization of charge carriers for photocatalysis. Additionally, Pd supported on medium sized anatase (∼16 nm) hinders the formation of O2•- radicals on TiO2 surfaces, thus preventing unwanted reoxidation of photogenerated H2.

    Original languageEnglish
    Pages (from-to)4239-4247
    Number of pages9
    JournalACS Catalysis
    Issue number7
    Publication statusPublished - 1 Jul 2016


    • density functional theory
    • electron spin resonance
    • hydrogen evolution
    • metal-semiconductor interaction
    • phenol decomposition
    • photocatalysis
    • TiO


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