Measurement and modeling of the high-pressure behavior of the binary system carbon dioxide + 1,2-epoxycyclohexane

M.A. Schilt, van, R.M. Wering, M.F. Kemmere, T.W. Loos, de, J.T.F. Keurentjes

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    18 Citations (Scopus)

    Abstract

    Experimental bubble point isopleths for the binary system carbon dioxide + 1,2-epoxycyclohexane have been determined for mole fractions from (10 to 50) % CO2 and temperatures from (354 to 424) K. Vapor pressures and liquid densities of pure 1,2-epoxycyclohexane have been measured from (361 to 474) K and from (278 to 363) K, respectively. Using the Peng-Robinson equation of state and van der Waals one-fluid mixing rules, a good description of the phase behavior of both the vapor pressure and the bubble point data has been obtained. The binary interaction parameter kij has been found to be temperature-dependent.
    Original languageEnglish
    Pages (from-to)1879-1882
    JournalJournal of Chemical and Engineering Data
    Volume50
    Issue number6
    DOIs
    Publication statusPublished - 2005

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