Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks

Vincent Marichez; Akihiro Sato; Peter A. Dunne; Jorge Leira-Iglesias; Georges J.M. Formon; Michaela K. Schicho; Isja de Feijter; Pascal Hébraud; Matthieu Bailleul; Pol Besenius; Munuswamy Venkatesan; J.M.D. Coey; E.W. Meijer; Thomas M. Hermans

doi:10.1021/jacs.1c05053

Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks

Vincent Marichez
, Akihiro Sato
, Peter A. Dunne
, Jorge Leira-Iglesias
, Georges J.M. Formon
, Michaela K. Schicho
, Isja de Feijter
, Pascal Hébraud
, Matthieu Bailleul
, Pol Besenius
, Munuswamy Venkatesan
, J.M.D. Coey
, E.W. Meijer
, Thomas M. Hermans (Corresponding author)

Research output: Contribution to journal › Article › Academic › peer-review

5 Citations (Scopus)

Abstract

Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.

Original language	English
Pages (from-to)	11914-11918
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	143
Issue number	31
DOIs	https://doi.org/10.1021/jacs.1c05053
Publication status	Published - 11 Aug 2021

Funding

V.M., A.S., J.L.-I., and T.M.H. would like to acknowledge the funding from ANR-10-LABX-0026 CSC. G.J.M.F. received funding from Ministère de l’Education Nationale de l’Enseignement supérieur et de la Recherche. E.W.M. acknowledges funding of the Dutch Ministry of Education, Culture and Science (Gravitation program 024.001.035). P.D. and T.M.H. acknowledge the support of the Labex NIE 11-LABX-0058_NIE within the Investissement d’Avenir program ANR-10-IDEX-0002-02, and the support of the University of Strasbourg Institute for Advanced Studies (USIAS) Fellowship. P.A.D. acknowledges support from SALTYSPIN ANR-17-CE09-0005. M.V. was funded by Science Foundation Ireland grant 16/IA/4534 ZEMS. T.M.H. received support from ERC-Stg 757910. J.M.D.C. acknowledges a Gutenberg visiting professorship from the University of Strasbourg

Funders	Funder number
European Union's Horizon 2020 - Research and Innovation Framework Programme	757910
Science Foundation Ireland - SFI	16/IA/4534 ZEMS
Ministerie van Onderwijs, Cultuur en Wetenschap	ANR-10-IDEX-0002-02, 024.001.035

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10.1021/jacs.1c05053

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Marichez, V., Sato, A., Dunne, P. A., Leira-Iglesias, J., Formon, G. J. M., Schicho, M. K., de Feijter, I., Hébraud, P., Bailleul, M., Besenius, P., Venkatesan, M., Coey, J. M. D., Meijer, E. W., & Hermans, T. M. (2021). Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks. Journal of the American Chemical Society, 143(31), 11914-11918. https://doi.org/10.1021/jacs.1c05053

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abstract = "Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.",

author = "Vincent Marichez and Akihiro Sato and Dunne, \{Peter A.\} and Jorge Leira-Iglesias and Formon, \{Georges J.M.\} and Schicho, \{Michaela K.\} and \{de Feijter\}, Isja and Pascal H{\'e}braud and Matthieu Bailleul and Pol Besenius and Munuswamy Venkatesan and J.M.D. Coey and E.W. Meijer and Hermans, \{Thomas M.\}",

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Marichez, V, Sato, A, Dunne, PA, Leira-Iglesias, J, Formon, GJM, Schicho, MK, de Feijter, I, Hébraud, P, Bailleul, M, Besenius, P, Venkatesan, M, Coey, JMD, Meijer, EW & Hermans, TM 2021, 'Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks', Journal of the American Chemical Society, vol. 143, no. 31, pp. 11914-11918. https://doi.org/10.1021/jacs.1c05053

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T1 - Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks

AU - Marichez, Vincent

AU - Sato, Akihiro

AU - Dunne, Peter A.

AU - Leira-Iglesias, Jorge

AU - Formon, Georges J.M.

AU - Schicho, Michaela K.

AU - de Feijter, Isja

AU - Hébraud, Pascal

AU - Bailleul, Matthieu

AU - Besenius, Pol

AU - Venkatesan, Munuswamy

AU - Coey, J.M.D.

AU - Meijer, E.W.

AU - Hermans, Thomas M.

PY - 2021/8/11

Y1 - 2021/8/11

N2 - Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.

AB - Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.

UR - https://www.scopus.com/pages/publications/85113154428

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EP - 11918

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 31

ER -

Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks

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