Macromolecular materials in heterogeneous catalysis: an aluminium silasesquioxane gel as active catalyst in Diels-Alder reactions of enones

H.C.L. Abbenhuis, H.W.G. Herwijnen, van, R.A. Santen, van

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

A highly active, genuinely heterogeneous catalyst for liquid- phase Diels-Alder reactions of enones results from the silanol centred modification of an incompletely condensed silasesquioxane with trimethylaluminium, the resulting catalytic material being a gel that contains aluminium(III) siloxy functions (Al-O-Si) which are incorporated in a well defined, three-dimensional SiO framework
Original languageEnglish
Pages (from-to)1941-1942
Number of pages2
JournalChemical Communications
Volume1996
Issue number16
DOIs
Publication statusPublished - 1996

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