TY - JOUR
T1 - Long-lived charge-transfer state from B−N frustrated Lewis pairs enchained in supramolecular copolymers
AU - Adelizzi, Beatrice
AU - Chidchob, Pongphak
AU - Tanaka, Naoki
AU - Lamers, Brigitte A.G.
AU - Meskers, Stefan C.J.
AU - Ogi, Soichiro
AU - Palmans, Anja R.A.
AU - Yamaguchi, Shigehiro
AU - Meijer, E. W.
PY - 2020/9/30
Y1 - 2020/9/30
N2 - The field of supramolecular polymers is rapidly expanding; however, the exploitation of these systems as functional materials is still elusive. To become competitive, supramolecular polymers must display microstructural order and the emergence of new properties upon copolymerization. To tackle this, a greater understanding of the relationship between monomers’ design and polymer microstructure is required as well as a set of functional monomers that efficiently interact with one another to synergistically generate new properties upon copolymerization. Here, we present the first implementation of frustrated Lewis pairs into supramolecular copolymers. Two supramolecular copolymers based on π-conjugated O-bridged triphenylborane and two different triphenylamines display the formation of B−N pairs within the supramolecular chain. The remarkably long lifetime and the circularly polarized nature of the resulting photoluminescence emission highlight the possibility to obtain an intermolecular B−N charge transfer. These results are proposed to be the consequences of the enchainment of B−N frustrated Lewis pairs within 1D supramolecular aggregates. Although it is challenging to obtain a precise molecular picture of the copolymer microstructure, the formation of random blocklike copolymers could be deduced from a combination of optical spectroscopic techniques and theoretical simulation.
AB - The field of supramolecular polymers is rapidly expanding; however, the exploitation of these systems as functional materials is still elusive. To become competitive, supramolecular polymers must display microstructural order and the emergence of new properties upon copolymerization. To tackle this, a greater understanding of the relationship between monomers’ design and polymer microstructure is required as well as a set of functional monomers that efficiently interact with one another to synergistically generate new properties upon copolymerization. Here, we present the first implementation of frustrated Lewis pairs into supramolecular copolymers. Two supramolecular copolymers based on π-conjugated O-bridged triphenylborane and two different triphenylamines display the formation of B−N pairs within the supramolecular chain. The remarkably long lifetime and the circularly polarized nature of the resulting photoluminescence emission highlight the possibility to obtain an intermolecular B−N charge transfer. These results are proposed to be the consequences of the enchainment of B−N frustrated Lewis pairs within 1D supramolecular aggregates. Although it is challenging to obtain a precise molecular picture of the copolymer microstructure, the formation of random blocklike copolymers could be deduced from a combination of optical spectroscopic techniques and theoretical simulation.
UR - http://www.scopus.com/inward/record.url?scp=85092431861&partnerID=8YFLogxK
U2 - 10.1021/jacs.0c06921
DO - 10.1021/jacs.0c06921
M3 - Article
C2 - 32880167
AN - SCOPUS:85092431861
SN - 0002-7863
VL - 142
SP - 16681
EP - 16689
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 39
ER -