Liquid crystal networks on thermoplastics : reprogrammable photo-responsive actuators

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Abstract

Arbitrary shape (re)programming is appealing for fabricating, untethered shape‐morphing photo actuators with intricate configurations and features. We present re‐programmable light responsive thermoplastic actuators with arbitrary initial shapes through spray‐coating of polyethylene terephthalate (PET) with an azobenzene‐doped light responsive liquid crystal network (LCN). The initial geometry of the actuator is controlled by thermally shaping and fixing the thermoplastic PET, allowing arbitrary shapes, including origami‐like folds and left and right handed helicity within a single sample. The thermally fixed geometries can be reversibly actuated through light exposure, with fast, reversible area‐specific actuation, such as winding, unwinding and unfolding. By shape re‐programming, the same sample can be re‐designed and light actuated again. The strategy presented here demonstrates easy fabrication of mechanically robust, recyclable, photo‐responsive actuators with highly tuneable geometries and actuation modes.
Original languageEnglish
Pages (from-to)4532-4536
Number of pages5
JournalAngewandte Chemie - International Edition
Volume59
Issue number11
Early online date10 Jan 2020
DOIs
Publication statusPublished - 9 Mar 2020

Keywords

  • liquid crystals
  • photo-responsive materials
  • polymers
  • reprogrammability
  • thermoplastic

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