Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers

H. Hofmeier; S. Schmatloch; D. Wouters; U.S. Schubert

doi:10.1002/macp.200300011

Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers

H. Hofmeier
, S. Schmatloch
, D. Wouters
, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

94 Citations (Scopus)

Abstract

In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly(ethylene glycol)s and terpyridine ruthenium(II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.

Original language	English
Pages (from-to)	2197-2203
Journal	Macromolecular Chemistry and Physics
Volume	204
Issue number	18
DOIs	https://doi.org/10.1002/macp.200300011
Publication status	Published - 2003

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10.1002/macp.200300011

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title = "Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers",

abstract = "In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly(ethylene glycol)s and terpyridine ruthenium(II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.",

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year = "2003",

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T1 - Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers

AU - Hofmeier, H.

AU - Schmatloch, S.

AU - Wouters, D.

AU - Schubert, U.S.

PY - 2003

Y1 - 2003

N2 - In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly(ethylene glycol)s and terpyridine ruthenium(II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.

AB - In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly(ethylene glycol)s and terpyridine ruthenium(II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.

U2 - 10.1002/macp.200300011

DO - 10.1002/macp.200300011

M3 - Article

SN - 1022-1352

VL - 204

SP - 2197

EP - 2203

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 18

ER -

Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers

Abstract

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