TY - JOUR
T1 - Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers
AU - Hofmeier, H.
AU - Schmatloch, S.
AU - Wouters, D.
AU - Schubert, U.S.
PY - 2003
Y1 - 2003
N2 - In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly(ethylene glycol)s and terpyridine ruthenium(II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.
AB - In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly(ethylene glycol)s and terpyridine ruthenium(II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.
U2 - 10.1002/macp.200300011
DO - 10.1002/macp.200300011
M3 - Article
SN - 1022-1352
VL - 204
SP - 2197
EP - 2203
JO - Macromolecular Chemistry and Physics
JF - Macromolecular Chemistry and Physics
IS - 18
ER -