Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid

E.E. Havinga; M.M. Bouman; E.W. Meijer; A. Pomp; M.M.J. Simenon

doi:10.1016/0379-6779(94)90168-6

Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid

E.E. Havinga, M.M. Bouman, E.W. Meijer, A. Pomp, M.M.J. Simenon

Macromolecular and Organic Chemistry

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Abstract

A large induced CD is found in the conduction band of polyaniline doped with optically active camphorsulfonic acid. In films obtained by spin-coating from a m-cresol soln., the chiral dopant induces chirality within the main chain of polyaniline. No other combinations of achiral conducting polymers and chiral dopants have been found that show induced optical activity in their conduction band.

Original language	English
Pages (from-to)	93-97
Number of pages	5
Journal	Synthetic Metals
Volume	66
Issue number	1
DOIs	https://doi.org/10.1016/0379-6779(94)90168-6
Publication status	Published - 1994

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title = "Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid",

abstract = "A large induced CD is found in the conduction band of polyaniline doped with optically active camphorsulfonic acid. In films obtained by spin-coating from a m-cresol soln., the chiral dopant induces chirality within the main chain of polyaniline. No other combinations of achiral conducting polymers and chiral dopants have been found that show induced optical activity in their conduction band.",

author = "E.E. Havinga and M.M. Bouman and E.W. Meijer and A. Pomp and M.M.J. Simenon",

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T1 - Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid

AU - Havinga, E.E.

AU - Bouman, M.M.

AU - Meijer, E.W.

AU - Pomp, A.

AU - Simenon, M.M.J.

PY - 1994

Y1 - 1994

N2 - A large induced CD is found in the conduction band of polyaniline doped with optically active camphorsulfonic acid. In films obtained by spin-coating from a m-cresol soln., the chiral dopant induces chirality within the main chain of polyaniline. No other combinations of achiral conducting polymers and chiral dopants have been found that show induced optical activity in their conduction band.

AB - A large induced CD is found in the conduction band of polyaniline doped with optically active camphorsulfonic acid. In films obtained by spin-coating from a m-cresol soln., the chiral dopant induces chirality within the main chain of polyaniline. No other combinations of achiral conducting polymers and chiral dopants have been found that show induced optical activity in their conduction band.

U2 - 10.1016/0379-6779(94)90168-6

DO - 10.1016/0379-6779(94)90168-6

M3 - Article

VL - 66

SP - 93

EP - 97

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1

ER -

Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid

Abstract

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