Kolbe and persulfate electrosyntheses

Willem Smit

doi:10.1016/0013-4686(71)85176-9

Kolbe and persulfate electrosyntheses

Willem Smit

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

4 Citations (Scopus)

Abstract

During S2O82- electrosynthesis, as sufficiently high potentials, a Pt anode in the SO42- soln. is covered by adsorbed SO42- species, the oxide-covered Pt becoming limited to isolated patches. The adsorption was obsd. by detns. of current efficiencies and potentials as a function of the concn. of S-contg. species at const. temp. and at various const. c.ds. The adsorbed SO42- essentially do not participate further in S2O82- formation, and SO42-, not HSO4-, are discharged on the SO42-covered areas of the electrode. The intermediates are formed in a nonadsorbed state and must be considered to be free radicals. [on SciFinder (R)]

Original language	English
Pages (from-to)	653-654
Number of pages	2
Journal	Electrochimica Acta
Volume	16
Issue number	5
DOIs	https://doi.org/10.1016/0013-4686(71)85176-9
Publication status	Published - 1971

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title = "Kolbe and persulfate electrosyntheses",

abstract = "During S2O82- electrosynthesis, as sufficiently high potentials, a Pt anode in the SO42- soln. is covered by adsorbed SO42- species, the oxide-covered Pt becoming limited to isolated patches. The adsorption was obsd. by detns. of current efficiencies and potentials as a function of the concn. of S-contg. species at const. temp. and at various const. c.ds. The adsorbed SO42- essentially do not participate further in S2O82- formation, and SO42-, not HSO4-, are discharged on the SO42-covered areas of the electrode. The intermediates are formed in a nonadsorbed state and must be considered to be free radicals. [on SciFinder (R)]",

author = "Willem Smit",

year = "1971",

doi = "10.1016/0013-4686(71)85176-9",

language = "English",

volume = "16",

pages = "653--654",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier",

number = "5",

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TY - JOUR

T1 - Kolbe and persulfate electrosyntheses

AU - Smit, Willem

PY - 1971

Y1 - 1971

N2 - During S2O82- electrosynthesis, as sufficiently high potentials, a Pt anode in the SO42- soln. is covered by adsorbed SO42- species, the oxide-covered Pt becoming limited to isolated patches. The adsorption was obsd. by detns. of current efficiencies and potentials as a function of the concn. of S-contg. species at const. temp. and at various const. c.ds. The adsorbed SO42- essentially do not participate further in S2O82- formation, and SO42-, not HSO4-, are discharged on the SO42-covered areas of the electrode. The intermediates are formed in a nonadsorbed state and must be considered to be free radicals. [on SciFinder (R)]

AB - During S2O82- electrosynthesis, as sufficiently high potentials, a Pt anode in the SO42- soln. is covered by adsorbed SO42- species, the oxide-covered Pt becoming limited to isolated patches. The adsorption was obsd. by detns. of current efficiencies and potentials as a function of the concn. of S-contg. species at const. temp. and at various const. c.ds. The adsorbed SO42- essentially do not participate further in S2O82- formation, and SO42-, not HSO4-, are discharged on the SO42-covered areas of the electrode. The intermediates are formed in a nonadsorbed state and must be considered to be free radicals. [on SciFinder (R)]

U2 - 10.1016/0013-4686(71)85176-9

DO - 10.1016/0013-4686(71)85176-9

M3 - Article

SN - 0013-4686

VL - 16

SP - 653

EP - 654

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 5

ER -

Kolbe and persulfate electrosyntheses

Abstract

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