Kinetics and mechanism of chlorine evolution on metaloxide electrodes

L.J.J. Janssen

Kinetics and mechanism of chlorine evolution on metaloxide electrodes

L.J.J. Janssen

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

The mechanisms and the data of kinetic parameters given in literature for the chlorine evolution on various types of Ru02/Ti02 electrodes are discussed. Moreover, some new experimental results are given. It has been concluded that the chlorine evolution on this type of electrode occurs according to the Volmer— Heyrowsky mechanism, where the Volmer reaction is in quasi equilibrium and the Heyrowsky reaction and eventually the diffusion of molecular chlorine away from the electrode surface into the bulk of the solution determine the potential— current density relation.

Original language	English
Title of host publication	Modern chlor-alkali technology, vol. 2
Editors	C. Jackson
Place of Publication	Chichester
Publisher	Ellis Horwood
Pages	271-286
ISBN (Print)	0-85312-525-2
Publication status	Published - 1983

Cite this

@inproceedings{5cadf27bed5c47ea9daee9493827b984,

title = "Kinetics and mechanism of chlorine evolution on metaloxide electrodes",

abstract = "The mechanisms and the data of kinetic parameters given in literature for the chlorine evolution on various types of Ru02/Ti02 electrodes are discussed. Moreover, some new experimental results are given. It has been concluded that the chlorine evolution on this type of electrode occurs according to the Volmer— Heyrowsky mechanism, where the Volmer reaction is in quasi equilibrium and the Heyrowsky reaction and eventually the diffusion of molecular chlorine away from the electrode surface into the bulk of the solution determine the potential— current density relation.",

author = "L.J.J. Janssen",

year = "1983",

language = "English",

isbn = "0-85312-525-2",

pages = "271--286",

editor = "C. Jackson",

booktitle = "Modern chlor-alkali technology, vol. 2",

publisher = "Ellis Horwood",

}

TY - GEN

T1 - Kinetics and mechanism of chlorine evolution on metaloxide electrodes

AU - Janssen, L.J.J.

PY - 1983

Y1 - 1983

N2 - The mechanisms and the data of kinetic parameters given in literature for the chlorine evolution on various types of Ru02/Ti02 electrodes are discussed. Moreover, some new experimental results are given. It has been concluded that the chlorine evolution on this type of electrode occurs according to the Volmer— Heyrowsky mechanism, where the Volmer reaction is in quasi equilibrium and the Heyrowsky reaction and eventually the diffusion of molecular chlorine away from the electrode surface into the bulk of the solution determine the potential— current density relation.

AB - The mechanisms and the data of kinetic parameters given in literature for the chlorine evolution on various types of Ru02/Ti02 electrodes are discussed. Moreover, some new experimental results are given. It has been concluded that the chlorine evolution on this type of electrode occurs according to the Volmer— Heyrowsky mechanism, where the Volmer reaction is in quasi equilibrium and the Heyrowsky reaction and eventually the diffusion of molecular chlorine away from the electrode surface into the bulk of the solution determine the potential— current density relation.

M3 - Conference contribution

SN - 0-85312-525-2

SP - 271

EP - 286

BT - Modern chlor-alkali technology, vol. 2

A2 - Jackson, C.

PB - Ellis Horwood

CY - Chichester

ER -

Kinetics and mechanism of chlorine evolution on metaloxide electrodes

Abstract

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