Kinetics and mechanism of chemical reactions in H2/O2/N2 flames at atmospheric pressure

O.P. Korobeinichev, A.G. Shmakov, I.V. Rybitskaya, T.A. Bolshova, D.A. Chernov, D.A. Knyazkov, A.A. Konnov

    Research output: Contribution to journalArticleAcademicpeer-review

    15 Citations (Scopus)
    1 Downloads (Pure)

    Abstract

    The kinetics and mechanism of chemical reactions in the H2/O2/N2 flame were studied experimentally and by simulating the structure of premixed laminar flat atmospheric H2/O2/N2 flames of different initial compositions. The concentration profiles for stable compounds (H2, O2, and H2O), H atoms, and OH• radicals in flames were measured by molecular-beam sampling mass spectrometry using soft electron-impact ionization. The experimental data thus obtained are in good agreement with the results of simulations in terms of three familiar kinetic mechanisms, suggesting that these mechanisms are applicable to the description of the flame structure in hydrogen-oxygen mixtures at atmospheric pressure.
    Original languageEnglish
    Pages (from-to)170-175
    JournalKinetics and Catalysis
    Volume50
    DOIs
    Publication statusPublished - 2009

    Fingerprint

    Dive into the research topics of 'Kinetics and mechanism of chemical reactions in H2/O2/N2 flames at atmospheric pressure'. Together they form a unique fingerprint.

    Cite this