Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

M. Geus, de; J.W. Peeters; M. Wolffs; T.M. Hermans; A.R.A. Palmans; C.E. Koning; A. Heise

doi:10.1021/ma0473871

Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

M. Geus, de
, J.W. Peeters
, M. Wolffs
, T.M. Hermans
, A.R.A. Palmans
, C.E. Koning
, A. Heise

Research output: Contribution to journal › Article › Academic › peer-review

66 Citations (Scopus)

Abstract

The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to

Original language	English
Pages (from-to)	4220-4225
Journal	Macromolecules
Volume	38
Issue number	10
DOIs	https://doi.org/10.1021/ma0473871
Publication status	Published - 2005

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10.1021/ma0473871

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abstract = "The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to",

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T1 - Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

AU - Geus, de, M.

AU - Peeters, J.W.

AU - Wolffs, M.

AU - Hermans, T.M.

AU - Palmans, A.R.A.

AU - Koning, C.E.

AU - Heise, A.

PY - 2005

Y1 - 2005

N2 - The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to

AB - The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to

U2 - 10.1021/ma0473871

DO - 10.1021/ma0473871

M3 - Article

SN - 0024-9297

VL - 38

SP - 4220

EP - 4225

JO - Macromolecules

JF - Macromolecules

IS - 10

ER -

Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

Abstract

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