Investigation into the initialization behaviour of RAFT-mediated styrene-maleic anhydride copolymerizations

E. van den Dungen; J. Rinquest; N.O. Pretorius; J.M. McKenzie; J.B. McLeary; R.D. Sanderson; B. Klumperman

doi:10.1071/CH06238

Investigation into the initialization behaviour of RAFT-mediated styrene-maleic anhydride copolymerizations

E. van den Dungen, J. Rinquest, N.O. Pretorius, J.M. McKenzie, J.B. McLeary, R.D. Sanderson, B. Klumperman

Chemical Engineering and Chemistry

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Abstract

The living radical alternating copolymerization of styrene and maleic anhydride mediated by the reversible addition–fragmentation chain transfer (RAFT) polymerization process has been studied at short chain lengths using two different dithiobenzoate RAFT agents. The results indicate specificity of addition of the RAFT-agent leaving groups for either styrene or maleic anhydride. The addition rate of the monomers and the fact that monomers are added individually favour the penultimate unit model of polymer propagation

Original language	English
Pages (from-to)	742-748
Journal	Australian Journal of Chemistry
Volume	59
Issue number	10
DOIs	https://doi.org/10.1071/CH06238
Publication status	Published - 2006

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10.1071/CH06238

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title = "Investigation into the initialization behaviour of RAFT-mediated styrene-maleic anhydride copolymerizations",

abstract = "The living radical alternating copolymerization of styrene and maleic anhydride mediated by the reversible addition–fragmentation chain transfer (RAFT) polymerization process has been studied at short chain lengths using two different dithiobenzoate RAFT agents. The results indicate specificity of addition of the RAFT-agent leaving groups for either styrene or maleic anhydride. The addition rate of the monomers and the fact that monomers are added individually favour the penultimate unit model of polymer propagation",

author = "{van den Dungen}, E. and J. Rinquest and N.O. Pretorius and J.M. McKenzie and J.B. McLeary and R.D. Sanderson and B. Klumperman",

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AU - van den Dungen, E.

AU - Rinquest, J.

AU - Pretorius, N.O.

AU - McKenzie, J.M.

AU - McLeary, J.B.

AU - Sanderson, R.D.

AU - Klumperman, B.

PY - 2006

Y1 - 2006

N2 - The living radical alternating copolymerization of styrene and maleic anhydride mediated by the reversible addition–fragmentation chain transfer (RAFT) polymerization process has been studied at short chain lengths using two different dithiobenzoate RAFT agents. The results indicate specificity of addition of the RAFT-agent leaving groups for either styrene or maleic anhydride. The addition rate of the monomers and the fact that monomers are added individually favour the penultimate unit model of polymer propagation

AB - The living radical alternating copolymerization of styrene and maleic anhydride mediated by the reversible addition–fragmentation chain transfer (RAFT) polymerization process has been studied at short chain lengths using two different dithiobenzoate RAFT agents. The results indicate specificity of addition of the RAFT-agent leaving groups for either styrene or maleic anhydride. The addition rate of the monomers and the fact that monomers are added individually favour the penultimate unit model of polymer propagation

U2 - 10.1071/CH06238

DO - 10.1071/CH06238

M3 - Article

SN - 0004-9425

VL - 59

SP - 742

EP - 748

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 10

ER -

Investigation into the initialization behaviour of RAFT-mediated styrene-maleic anhydride copolymerizations

Abstract

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