Intramolecular charge transfer in some donor-acceptor molecules as N-picrylauramine

F.W.E. Knoop; H.M. Buck; L.J. Oosterhoff

doi:10.1002/recl.19680870714

Intramolecular charge transfer in some donor-acceptor molecules as N-picrylauramine

F.W.E. Knoop, H.M. Buck, L.J. Oosterhoff

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

2 Citations (Scopus)

Abstract

Intramolecular charge transfer in picryl derivatives of benzophenonimide has been studied. Dipole moments and NMR spectra reveal that the contribution of charge transfer structures to the ground state is of minor importance in contrast with what could be expected. The discrepancy can be explained if a geometrical structure is assumed which closely resembles that of N,N-diphenyl-N'-picrylhydrazyl.

Original language	English
Pages (from-to)	847-860
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	87
Issue number	7
DOIs	https://doi.org/10.1002/recl.19680870714
Publication status	Published - 1968

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title = "Intramolecular charge transfer in some donor-acceptor molecules as N-picrylauramine",

abstract = "Intramolecular charge transfer in picryl derivatives of benzophenonimide has been studied. Dipole moments and NMR spectra reveal that the contribution of charge transfer structures to the ground state is of minor importance in contrast with what could be expected. The discrepancy can be explained if a geometrical structure is assumed which closely resembles that of N,N-diphenyl-N'-picrylhydrazyl.",

author = "F.W.E. Knoop and H.M. Buck and L.J. Oosterhoff",

year = "1968",

doi = "10.1002/recl.19680870714",

language = "English",

volume = "87",

pages = "847--860",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

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T1 - Intramolecular charge transfer in some donor-acceptor molecules as N-picrylauramine

AU - Knoop, F.W.E.

AU - Buck, H.M.

AU - Oosterhoff, L.J.

PY - 1968

Y1 - 1968

N2 - Intramolecular charge transfer in picryl derivatives of benzophenonimide has been studied. Dipole moments and NMR spectra reveal that the contribution of charge transfer structures to the ground state is of minor importance in contrast with what could be expected. The discrepancy can be explained if a geometrical structure is assumed which closely resembles that of N,N-diphenyl-N'-picrylhydrazyl.

AB - Intramolecular charge transfer in picryl derivatives of benzophenonimide has been studied. Dipole moments and NMR spectra reveal that the contribution of charge transfer structures to the ground state is of minor importance in contrast with what could be expected. The discrepancy can be explained if a geometrical structure is assumed which closely resembles that of N,N-diphenyl-N'-picrylhydrazyl.

U2 - 10.1002/recl.19680870714

DO - 10.1002/recl.19680870714

M3 - Article

SN - 0165-0513

VL - 87

SP - 847

EP - 860

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 7

ER -

Intramolecular charge transfer in some donor-acceptor molecules as N-picrylauramine

Abstract

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