Interpretation of Solvent Effects on Styrene/Maleic Anhydride Copolymer Sequence Distribution and Microstructure in Terms of the Bootstrap Effect

L. Klumperman; P.G. Brown

doi:10.1021/ma00099a023

Interpretation of Solvent Effects on Styrene/Maleic Anhydride Copolymer Sequence Distribution and Microstructure in Terms of the Bootstrap Effect

L. Klumperman, P.G. Brown

Chemical Engineering and Chemistry

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Abstract

Solvent effects on the copolymn. of styrene and maleic anhydride are interpreted in terms of Harwood's bootstrap effect. Earlier observations that this comonomer pair behaves according to the bootstrap effect are confirmed. Furthermore, solvent effects on stereochem. configuration can be interpreted in terms of the bootstrap effect as well. The observation that the cis/trans (Z/E) ratio (Zusammen/Entgegen) of the anhydride units vs. copolymer compn. is independent of solvent is attributed to monomer partitioning between the bulk of the soln. and the locus of polymn

Original language	English
Pages (from-to)	6100-6101
Journal	Macromolecules
Volume	27
Issue number	21
DOIs	https://doi.org/10.1021/ma00099a023
Publication status	Published - 1994

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title = "Interpretation of Solvent Effects on Styrene/Maleic Anhydride Copolymer Sequence Distribution and Microstructure in Terms of the Bootstrap Effect",

abstract = "Solvent effects on the copolymn. of styrene and maleic anhydride are interpreted in terms of Harwood's bootstrap effect. Earlier observations that this comonomer pair behaves according to the bootstrap effect are confirmed. Furthermore, solvent effects on stereochem. configuration can be interpreted in terms of the bootstrap effect as well. The observation that the cis/trans (Z/E) ratio (Zusammen/Entgegen) of the anhydride units vs. copolymer compn. is independent of solvent is attributed to monomer partitioning between the bulk of the soln. and the locus of polymn",

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AU - Klumperman, L.

AU - Brown, P.G.

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N2 - Solvent effects on the copolymn. of styrene and maleic anhydride are interpreted in terms of Harwood's bootstrap effect. Earlier observations that this comonomer pair behaves according to the bootstrap effect are confirmed. Furthermore, solvent effects on stereochem. configuration can be interpreted in terms of the bootstrap effect as well. The observation that the cis/trans (Z/E) ratio (Zusammen/Entgegen) of the anhydride units vs. copolymer compn. is independent of solvent is attributed to monomer partitioning between the bulk of the soln. and the locus of polymn

AB - Solvent effects on the copolymn. of styrene and maleic anhydride are interpreted in terms of Harwood's bootstrap effect. Earlier observations that this comonomer pair behaves according to the bootstrap effect are confirmed. Furthermore, solvent effects on stereochem. configuration can be interpreted in terms of the bootstrap effect as well. The observation that the cis/trans (Z/E) ratio (Zusammen/Entgegen) of the anhydride units vs. copolymer compn. is independent of solvent is attributed to monomer partitioning between the bulk of the soln. and the locus of polymn

U2 - 10.1021/ma00099a023

DO - 10.1021/ma00099a023

M3 - Article

VL - 27

SP - 6100

EP - 6101

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 21

ER -

Interpretation of Solvent Effects on Styrene/Maleic Anhydride Copolymer Sequence Distribution and Microstructure in Terms of the Bootstrap Effect

Abstract

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