Internal structure of a thin film of mixed polymeric micelles on a solid/liquid interface

Ilja K. Voets; Wiebe M. de Vos; Bas Hofs; Arie de Keizer; Martien A. Conhen Stuart; Roland Steitz; Dieter Lott

doi:10.1021/jp709758p

Internal structure of a thin film of mixed polymeric micelles on a solid/liquid interface

Ilja K. Voets (Corresponding author), Wiebe M. de Vos, Bas Hofs, Arie de Keizer, Martien A. Conhen Stuart, Roland Steitz, Dieter Lott

Research output: Contribution to journal › Article › Academic › peer-review

22 Citations (Scopus)

Abstract

The adsorption of mixed micelles of poly(4-(2-amino hydrochloride- ethylthio)-butylene)-block-poly(ethylene oxide), PAETB₄₉-b-PEO ₂₁₂ and poly(4-(2-sodium carboxylate-ethylthio)-butylene)-block- poly(ethylene oxide), PCETB₄₇-_b-PEO₂₁₂ on solid/liquid interfaces has been studied with light, X-ray, and neutron reflectometry. The structure of the adsorbed layer can be described with a two-layer model consisting of an inner layer formed by the coacervate of the polyelectrolyte blocks PAETB₄₉ and PCETB₄₇ (∼1 nm) and an outer layer of PEO₂₁₂ blocks (∼6 nm). The micelles unfold upon adsorption forming a rather homogeneous flat layer that exposes its polyethylene oxide chains into the solution, thus rendering the surface antifouling after modification with the micelles.

Original language	English
Pages (from-to)	6937-6945
Number of pages	9
Journal	Journal of Physical Chemistry B
Volume	112
Issue number	23
DOIs	https://doi.org/10.1021/jp709758p
Publication status	Published - 12 Jun 2008
Externally published	Yes

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title = "Internal structure of a thin film of mixed polymeric micelles on a solid/liquid interface",

abstract = "The adsorption of mixed micelles of poly(4-(2-amino hydrochloride- ethylthio)-butylene)-block-poly(ethylene oxide), PAETB49-b-PEO 212 and poly(4-(2-sodium carboxylate-ethylthio)-butylene)-block- poly(ethylene oxide), PCETB47-b-PEO212 on solid/liquid interfaces has been studied with light, X-ray, and neutron reflectometry. The structure of the adsorbed layer can be described with a two-layer model consisting of an inner layer formed by the coacervate of the polyelectrolyte blocks PAETB49 and PCETB47 (∼1 nm) and an outer layer of PEO212 blocks (∼6 nm). The micelles unfold upon adsorption forming a rather homogeneous flat layer that exposes its polyethylene oxide chains into the solution, thus rendering the surface antifouling after modification with the micelles.",

author = "Voets, {Ilja K.} and {de Vos}, {Wiebe M.} and Bas Hofs and {de Keizer}, Arie and {Conhen Stuart}, {Martien A.} and Roland Steitz and Dieter Lott",

year = "2008",

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doi = "10.1021/jp709758p",

language = "English",

volume = "112",

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TY - JOUR

T1 - Internal structure of a thin film of mixed polymeric micelles on a solid/liquid interface

AU - Voets, Ilja K.

AU - de Vos, Wiebe M.

AU - Hofs, Bas

AU - de Keizer, Arie

AU - Conhen Stuart, Martien A.

AU - Steitz, Roland

AU - Lott, Dieter

PY - 2008/6/12

Y1 - 2008/6/12

N2 - The adsorption of mixed micelles of poly(4-(2-amino hydrochloride- ethylthio)-butylene)-block-poly(ethylene oxide), PAETB49-b-PEO 212 and poly(4-(2-sodium carboxylate-ethylthio)-butylene)-block- poly(ethylene oxide), PCETB47-b-PEO212 on solid/liquid interfaces has been studied with light, X-ray, and neutron reflectometry. The structure of the adsorbed layer can be described with a two-layer model consisting of an inner layer formed by the coacervate of the polyelectrolyte blocks PAETB49 and PCETB47 (∼1 nm) and an outer layer of PEO212 blocks (∼6 nm). The micelles unfold upon adsorption forming a rather homogeneous flat layer that exposes its polyethylene oxide chains into the solution, thus rendering the surface antifouling after modification with the micelles.

AB - The adsorption of mixed micelles of poly(4-(2-amino hydrochloride- ethylthio)-butylene)-block-poly(ethylene oxide), PAETB49-b-PEO 212 and poly(4-(2-sodium carboxylate-ethylthio)-butylene)-block- poly(ethylene oxide), PCETB47-b-PEO212 on solid/liquid interfaces has been studied with light, X-ray, and neutron reflectometry. The structure of the adsorbed layer can be described with a two-layer model consisting of an inner layer formed by the coacervate of the polyelectrolyte blocks PAETB49 and PCETB47 (∼1 nm) and an outer layer of PEO212 blocks (∼6 nm). The micelles unfold upon adsorption forming a rather homogeneous flat layer that exposes its polyethylene oxide chains into the solution, thus rendering the surface antifouling after modification with the micelles.

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U2 - 10.1021/jp709758p

DO - 10.1021/jp709758p

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SP - 6937

EP - 6945

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 23

ER -

Internal structure of a thin film of mixed polymeric micelles on a solid/liquid interface

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