Interaction potential between two spheres mediated by excluded volume polymers

R. Tuinier, H.N.W. Lekkerkerker, D.G.A.L. (Dirk) Aarts

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Abstract

The interaction between two spheres in a solution of nonadsorbing polymers, with excluded volume interaction, is calculated from the depletion layers around the spheres using the generalized Gibbs adsorption equation. By combining the bulk correlation length with the curvature-dependent interfacial tension between a sphere and the surrounding polymer solution [Hanke, Eisenriegler, and Dietrich, Phys. Rev. E 59, 6853 (1999)], the depletion layer thickness around a sphere is obtained. The resulting contact potential agrees with a scaling prediction of de Gennes in the semidilute regime.

Original languageEnglish
Article number060801
JournalPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
Volume65
Issue number6
DOIs
Publication statusPublished - Jun 2002
Externally publishedYes

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