Initialisation in RAFT-mediated polymerisation of methyl acrylate

J.B. McLeary; J.M. McKenzie; M.P. Tonge; R.D. Sanderson; B. Klumperman

doi:10.1039/b404857a

Initialisation in RAFT-mediated polymerisation of methyl acrylate

J.B. McLeary, J.M. McKenzie, M.P. Tonge, R.D. Sanderson, B. Klumperman

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

89 Citations (Scopus)

Abstract

Inhibition in Reversible Addn.-Fragmentation chain Transfer (RAFT)-mediated polymns. is currently a controversial issue; here we provide evidence that the slow \"propagation\" of the initiating and leaving group radicals during the early part (the period of consumption of the initial RAFT agent) of Me acrylate RAFT-mediated polymn. has characteristics similar to inhibition

Original language	English
Pages (from-to)	1950-1951
Journal	Chemical Communications, ChemComm
Volume	2004
Issue number	17
DOIs	https://doi.org/10.1039/b404857a
Publication status	Published - 2004

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10.1039/b404857a

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title = "Initialisation in RAFT-mediated polymerisation of methyl acrylate",

abstract = "Inhibition in Reversible Addn.-Fragmentation chain Transfer (RAFT)-mediated polymns. is currently a controversial issue; here we provide evidence that the slow \{"}propagation\{"} of the initiating and leaving group radicals during the early part (the period of consumption of the initial RAFT agent) of Me acrylate RAFT-mediated polymn. has characteristics similar to inhibition",

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AU - McLeary, J.B.

AU - McKenzie, J.M.

AU - Tonge, M.P.

AU - Sanderson, R.D.

AU - Klumperman, B.

PY - 2004

Y1 - 2004

N2 - Inhibition in Reversible Addn.-Fragmentation chain Transfer (RAFT)-mediated polymns. is currently a controversial issue; here we provide evidence that the slow \"propagation\" of the initiating and leaving group radicals during the early part (the period of consumption of the initial RAFT agent) of Me acrylate RAFT-mediated polymn. has characteristics similar to inhibition

AB - Inhibition in Reversible Addn.-Fragmentation chain Transfer (RAFT)-mediated polymns. is currently a controversial issue; here we provide evidence that the slow \"propagation\" of the initiating and leaving group radicals during the early part (the period of consumption of the initial RAFT agent) of Me acrylate RAFT-mediated polymn. has characteristics similar to inhibition

U2 - 10.1039/b404857a

DO - 10.1039/b404857a

M3 - Article

C2 - 15340616

VL - 2004

SP - 1950

EP - 1951

JO - Chemical Communications, ChemComm

JF - Chemical Communications, ChemComm

SN - 1359-7345

IS - 17

ER -

Initialisation in RAFT-mediated polymerisation of methyl acrylate

Abstract

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