Influence of preparation and composition on multicomponent molybdate catalysts for the selective oxidation of olefins

M.W.J. Wolfs, J.H.C. Hooff, van

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

3 Citations (Scopus)

Abstract

Catalysts with the composition MeII11-x Fex BiMo12On in which MeII= Ni, Co, Mg or Mn and 0 <× <4 are investigated. It is shown that preparation by coprecipitation followed by evaporation is necessary to obtain high activity and selectivity for the oxidation of propene to acrolein. Catalytic properties in combination with X-ray diffraction and ESCA measurements lead to a three-layer model for the catalyst particles. In this model the surface layer consists of Bi-molybdates, the second layer of Fe-molybdate and the core of MeII-molybdate. From the high specific activity of this type of catalysts compared with pure Bi-molybdates it is concluded that Fe-molybdate acts as a promotor. A possible explanation for this promoting effect is given.
Original languageEnglish
Title of host publicationPreparation of Catalysts I - Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the First International Symposium held at the Solvay Research Centre, Brussels
EditorsB. Delmon, P. Jacobs, G. Poncelet
Place of PublicationAmsterdam
PublisherElsevier
Pages161-176
ISBN (Print)9780444414281
DOIs
Publication statusPublished - 1976

Publication series

NameStudies in Surface Science and Catalysis
Volume1
ISSN (Print)0167-2991

Fingerprint

Alkenes
Oxidation
Catalysts
Chemical analysis
Acrolein
Coprecipitation
Evaporation
molybdate
X ray diffraction

Cite this

Wolfs, M. W. J., & Hooff, van, J. H. C. (1976). Influence of preparation and composition on multicomponent molybdate catalysts for the selective oxidation of olefins. In B. Delmon, P. Jacobs, & G. Poncelet (Eds.), Preparation of Catalysts I - Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the First International Symposium held at the Solvay Research Centre, Brussels (pp. 161-176). (Studies in Surface Science and Catalysis; Vol. 1). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(08)63950-6
Wolfs, M.W.J. ; Hooff, van, J.H.C. / Influence of preparation and composition on multicomponent molybdate catalysts for the selective oxidation of olefins. Preparation of Catalysts I - Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the First International Symposium held at the Solvay Research Centre, Brussels. editor / B. Delmon ; P. Jacobs ; G. Poncelet. Amsterdam : Elsevier, 1976. pp. 161-176 (Studies in Surface Science and Catalysis).
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abstract = "Catalysts with the composition MeII11-x Fex BiMo12On in which MeII= Ni, Co, Mg or Mn and 0 <× <4 are investigated. It is shown that preparation by coprecipitation followed by evaporation is necessary to obtain high activity and selectivity for the oxidation of propene to acrolein. Catalytic properties in combination with X-ray diffraction and ESCA measurements lead to a three-layer model for the catalyst particles. In this model the surface layer consists of Bi-molybdates, the second layer of Fe-molybdate and the core of MeII-molybdate. From the high specific activity of this type of catalysts compared with pure Bi-molybdates it is concluded that Fe-molybdate acts as a promotor. A possible explanation for this promoting effect is given.",
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Wolfs, MWJ & Hooff, van, JHC 1976, Influence of preparation and composition on multicomponent molybdate catalysts for the selective oxidation of olefins. in B Delmon, P Jacobs & G Poncelet (eds), Preparation of Catalysts I - Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the First International Symposium held at the Solvay Research Centre, Brussels. Studies in Surface Science and Catalysis, vol. 1, Elsevier, Amsterdam, pp. 161-176. https://doi.org/10.1016/S0167-2991(08)63950-6

Influence of preparation and composition on multicomponent molybdate catalysts for the selective oxidation of olefins. / Wolfs, M.W.J.; Hooff, van, J.H.C.

Preparation of Catalysts I - Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the First International Symposium held at the Solvay Research Centre, Brussels. ed. / B. Delmon; P. Jacobs; G. Poncelet. Amsterdam : Elsevier, 1976. p. 161-176 (Studies in Surface Science and Catalysis; Vol. 1).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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N2 - Catalysts with the composition MeII11-x Fex BiMo12On in which MeII= Ni, Co, Mg or Mn and 0 <× <4 are investigated. It is shown that preparation by coprecipitation followed by evaporation is necessary to obtain high activity and selectivity for the oxidation of propene to acrolein. Catalytic properties in combination with X-ray diffraction and ESCA measurements lead to a three-layer model for the catalyst particles. In this model the surface layer consists of Bi-molybdates, the second layer of Fe-molybdate and the core of MeII-molybdate. From the high specific activity of this type of catalysts compared with pure Bi-molybdates it is concluded that Fe-molybdate acts as a promotor. A possible explanation for this promoting effect is given.

AB - Catalysts with the composition MeII11-x Fex BiMo12On in which MeII= Ni, Co, Mg or Mn and 0 <× <4 are investigated. It is shown that preparation by coprecipitation followed by evaporation is necessary to obtain high activity and selectivity for the oxidation of propene to acrolein. Catalytic properties in combination with X-ray diffraction and ESCA measurements lead to a three-layer model for the catalyst particles. In this model the surface layer consists of Bi-molybdates, the second layer of Fe-molybdate and the core of MeII-molybdate. From the high specific activity of this type of catalysts compared with pure Bi-molybdates it is concluded that Fe-molybdate acts as a promotor. A possible explanation for this promoting effect is given.

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Wolfs MWJ, Hooff, van JHC. Influence of preparation and composition on multicomponent molybdate catalysts for the selective oxidation of olefins. In Delmon B, Jacobs P, Poncelet G, editors, Preparation of Catalysts I - Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the First International Symposium held at the Solvay Research Centre, Brussels. Amsterdam: Elsevier. 1976. p. 161-176. (Studies in Surface Science and Catalysis). https://doi.org/10.1016/S0167-2991(08)63950-6