TY - JOUR
T1 - In situ observation of transient reaction phenomena occurring on zeolite catalysts with the aid of positron emission profiling
AU - Van Santen, Rutger A.
AU - Anderson, B. G.
AU - Cunningham, R. H.
AU - Mangnus, A. V.G.
AU - Van Ijzendoorn, L. J.
AU - De Voigt, M. J.A.
PY - 1997/12/1
Y1 - 1997/12/1
N2 - The total concentrations of reactants and products within a flow-through reactor can be monitored as a function of both position and time by detecting gamma photons arising from the radioactive positron decay of injected 11C nuclei. The method was demonstrated by directly observing catalyst preconditioning and deactivation of a Pt/H-mordenite catalyst bed during the industrially important hexane hydroisomerization reaction.
AB - The total concentrations of reactants and products within a flow-through reactor can be monitored as a function of both position and time by detecting gamma photons arising from the radioactive positron decay of injected 11C nuclei. The method was demonstrated by directly observing catalyst preconditioning and deactivation of a Pt/H-mordenite catalyst bed during the industrially important hexane hydroisomerization reaction.
UR - http://www.scopus.com/inward/record.url?scp=0030484751&partnerID=8YFLogxK
U2 - 10.1002/anie.199627851
DO - 10.1002/anie.199627851
M3 - Article
SN - 1433-7851
VL - 35
SP - 2785
EP - 2787
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 23-24
ER -