Improved determination of overall rotational and vibronic relaxation rates of BaO (A1∑, v'=8, J'=49) colliding with Ar

T.G. Cats; J.G.M. Kuerten; M.I.M. Scheerboom; C.W.J.M. Klaasen; H.A. Dijkerman; C.T.J. Alkemade

doi:10.1016/0009-2614(84)85043-5

Improved determination of overall rotational and vibronic relaxation rates of BaO (A1∑, v'=8, J'=49) colliding with Ar

T.G. Cats
, J.G.M. Kuerten
, M.I.M. Scheerboom
, C.W.J.M. Klaasen
, H.A. Dijkerman
, C.T.J. Alkemade

Research output: Contribution to journal › Article › Academic › peer-review

1 Citation (Scopus)

2 Downloads (Pure)

Abstract

Using the linear dependence of the ratio of direct and indirect integrated rotational line fluorescence on the inverse. Ar pressure, we obtain more accurate rate constants for rotational relaxation. k = (91.3 ± 1.9) × 103 Pa-1 s-1 and for vibrational plus electronic relaxation: k = (21.0 ± 0.9) × 103 Pa-1 s-1 of cw-laser-excited BaO(A 1S, ¿' = 8, J'= 49) in collision with Ar. The experiments were performed on BaO produced in a gas-flow system using oxidants N2O, O2 and CO2 at variable argon pressures.

Original language	English
Pages (from-to)	347-350
Journal	Chemical Physics Letters
Volume	105
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(84)85043-5
Publication status	Published - 1984

Access to Document

10.1016/0009-2614(84)85043-5

Cite this

@article{252f97f23ab042eeaa626478357b90e2,

title = "Improved determination of overall rotational and vibronic relaxation rates of BaO (A1∑, v'=8, J'=49) colliding with Ar",

abstract = "Using the linear dependence of the ratio of direct and indirect integrated rotational line fluorescence on the inverse. Ar pressure, we obtain more accurate rate constants for rotational relaxation. k = (91.3 ± 1.9) × 103 Pa-1 s-1 and for vibrational plus electronic relaxation: k = (21.0 ± 0.9) × 103 Pa-1 s-1 of cw-laser-excited BaO(A 1S, ¿' = 8, J'= 49) in collision with Ar. The experiments were performed on BaO produced in a gas-flow system using oxidants N2O, O2 and CO2 at variable argon pressures.",

author = "T.G. Cats and J.G.M. Kuerten and M.I.M. Scheerboom and C.W.J.M. Klaasen and H.A. Dijkerman and C.T.J. Alkemade",

year = "1984",

doi = "10.1016/0009-2614(84)85043-5",

language = "English",

volume = "105",

pages = "347--350",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Improved determination of overall rotational and vibronic relaxation rates of BaO (A1∑, v'=8, J'=49) colliding with Ar

AU - Cats, T.G.

AU - Kuerten, J.G.M.

AU - Scheerboom, M.I.M.

AU - Klaasen, C.W.J.M.

AU - Dijkerman, H.A.

AU - Alkemade, C.T.J.

PY - 1984

Y1 - 1984

N2 - Using the linear dependence of the ratio of direct and indirect integrated rotational line fluorescence on the inverse. Ar pressure, we obtain more accurate rate constants for rotational relaxation. k = (91.3 ± 1.9) × 103 Pa-1 s-1 and for vibrational plus electronic relaxation: k = (21.0 ± 0.9) × 103 Pa-1 s-1 of cw-laser-excited BaO(A 1S, ¿' = 8, J'= 49) in collision with Ar. The experiments were performed on BaO produced in a gas-flow system using oxidants N2O, O2 and CO2 at variable argon pressures.

AB - Using the linear dependence of the ratio of direct and indirect integrated rotational line fluorescence on the inverse. Ar pressure, we obtain more accurate rate constants for rotational relaxation. k = (91.3 ± 1.9) × 103 Pa-1 s-1 and for vibrational plus electronic relaxation: k = (21.0 ± 0.9) × 103 Pa-1 s-1 of cw-laser-excited BaO(A 1S, ¿' = 8, J'= 49) in collision with Ar. The experiments were performed on BaO produced in a gas-flow system using oxidants N2O, O2 and CO2 at variable argon pressures.

U2 - 10.1016/0009-2614(84)85043-5

DO - 10.1016/0009-2614(84)85043-5

M3 - Article

SN - 0009-2614

VL - 105

SP - 347

EP - 350

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Improved determination of overall rotational and vibronic relaxation rates of BaO (A1∑, v'=8, J'=49) colliding with Ar

Abstract

Access to Document

Fingerprint

Cite this