Imaging of n-hexane in zeolites by positron emission profiling (PEP)

R.A. van Santen, B.G. Anderson, R.H. Cunningham, A.V.G. Mangnus, J. van Grondelle, L.J. IJzendoorn, van

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademic

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Abstract

Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse
Original languageEnglish
Title of host publication11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B
EditorsJ.W. Hightower, W.N. Delgass, E. Iglesia, A.T. Bell
Place of PublicationAmsterdam
PublisherElsevier
Pages791-800
ISBN (Print)0-444-81947-9
DOIs
Publication statusPublished - 1996
Event11th International Congress on Catalysis (ICC 1996) - Baltimore, MD, United States
Duration: 30 Jun 19965 Jul 1996
Conference number: 11

Publication series

NameStudies in Surface Science and Catalysis
NumberPart B
Volume101
ISSN (Print)0167-2991

Conference

Conference11th International Congress on Catalysis (ICC 1996)
Abbreviated titleICC 1996
CountryUnited States
CityBaltimore, MD
Period30/06/965/07/96

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zeolites
positrons
pulses
in situ measurement
alkenes
tracers
cyclotrons
partial pressure
molecules
temperature

Cite this

van Santen, R. A., Anderson, B. G., Cunningham, R. H., Mangnus, A. V. G., van Grondelle, J., & IJzendoorn, van, L. J. (1996). Imaging of n-hexane in zeolites by positron emission profiling (PEP). In J. W. Hightower, W. N. Delgass, E. Iglesia, & A. T. Bell (Eds.), 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B (pp. 791-800). (Studies in Surface Science and Catalysis; Vol. 101, No. Part B). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(96)80290-4
van Santen, R.A. ; Anderson, B.G. ; Cunningham, R.H. ; Mangnus, A.V.G. ; van Grondelle, J. ; IJzendoorn, van, L.J. / Imaging of n-hexane in zeolites by positron emission profiling (PEP). 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. editor / J.W. Hightower ; W.N. Delgass ; E. Iglesia ; A.T. Bell. Amsterdam : Elsevier, 1996. pp. 791-800 (Studies in Surface Science and Catalysis; Part B).
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abstract = "Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse",
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van Santen, RA, Anderson, BG, Cunningham, RH, Mangnus, AVG, van Grondelle, J & IJzendoorn, van, LJ 1996, Imaging of n-hexane in zeolites by positron emission profiling (PEP). in JW Hightower, WN Delgass, E Iglesia & AT Bell (eds), 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. Studies in Surface Science and Catalysis, no. Part B, vol. 101, Elsevier, Amsterdam, pp. 791-800, 11th International Congress on Catalysis (ICC 1996), Baltimore, MD, United States, 30/06/96. https://doi.org/10.1016/S0167-2991(96)80290-4

Imaging of n-hexane in zeolites by positron emission profiling (PEP). / van Santen, R.A.; Anderson, B.G.; Cunningham, R.H.; Mangnus, A.V.G.; van Grondelle, J.; IJzendoorn, van, L.J.

11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. ed. / J.W. Hightower; W.N. Delgass; E. Iglesia; A.T. Bell. Amsterdam : Elsevier, 1996. p. 791-800 (Studies in Surface Science and Catalysis; Vol. 101, No. Part B).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademic

TY - GEN

T1 - Imaging of n-hexane in zeolites by positron emission profiling (PEP)

AU - van Santen, R.A.

AU - Anderson, B.G.

AU - Cunningham, R.H.

AU - Mangnus, A.V.G.

AU - van Grondelle, J.

AU - IJzendoorn, van, L.J.

PY - 1996

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N2 - Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse

AB - Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse

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DO - 10.1016/S0167-2991(96)80290-4

M3 - Conference contribution

SN - 0-444-81947-9

T3 - Studies in Surface Science and Catalysis

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BT - 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B

A2 - Hightower, J.W.

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A2 - Iglesia, E.

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PB - Elsevier

CY - Amsterdam

ER -

van Santen RA, Anderson BG, Cunningham RH, Mangnus AVG, van Grondelle J, IJzendoorn, van LJ. Imaging of n-hexane in zeolites by positron emission profiling (PEP). In Hightower JW, Delgass WN, Iglesia E, Bell AT, editors, 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. Amsterdam: Elsevier. 1996. p. 791-800. (Studies in Surface Science and Catalysis; Part B). https://doi.org/10.1016/S0167-2991(96)80290-4