Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

F. Micciche; M.A. Straten, van; W. Ming; E. Oostveen; J. Haveren, van; R. Linde, van der; J.A. Reedijk

doi:10.1016/j.ijms.2005.08.014

Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

F. Micciche, M.A. Straten, van, W. Ming, E. Oostveen, J. Haveren, van, R. Linde, van der, J.A. Reedijk

Research output: Contribution to journal › Article › Academic › peer-review

12 Citations (Scopus)

Abstract

The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.

Original language	English
Pages (from-to)	80-83
Journal	Journal of Mass Spectrometry
Volume	246
Issue number	1-3
DOIs	https://doi.org/10.1016/j.ijms.2005.08.014
Publication status	Published - 2005

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title = "Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)",

abstract = "The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.",

author = "F. Micciche and {Straten, van}, M.A. and W. Ming and E. Oostveen and {Haveren, van}, J. and {Linde, van der}, R. and J.A. Reedijk",

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language = "English",

volume = "246",

pages = "80--83",

journal = "Journal of Mass Spectrometry",

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T1 - Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

AU - Micciche, F.

AU - Straten, van, M.A.

AU - Ming, W.

AU - Oostveen, E.

AU - Haveren, van, J.

AU - Linde, van der, R.

AU - Reedijk, J.A.

PY - 2005

Y1 - 2005

N2 - The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.

AB - The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.

U2 - 10.1016/j.ijms.2005.08.014

DO - 10.1016/j.ijms.2005.08.014

M3 - Article

SN - 1076-5174

VL - 246

SP - 80

EP - 83

JO - Journal of Mass Spectrometry

JF - Journal of Mass Spectrometry

IS - 1-3

ER -

Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

Abstract

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