Hydrodesulfurization catalysis by small metal sulfide particles

R.A. Santen, van; M.J. Vissenberg; G. Vorbeck; P.W. Bont, de; E. Boellaard; A.M. Kraan, van der; V.H.J. Beer, de

Hydrodesulfurization catalysis by small metal sulfide particles

R.A. Santen, van
, M.J. Vissenberg
, G. Vorbeck
, P.W. Bont, de
, E. Boellaard
, A.M. Kraan, van der
, V.H.J. Beer, de

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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Abstract

Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect

Original language	English
Title of host publication	Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994
Editors	Y. Izumi, H. Arai, M. Iwamoto
Place of Publication	Amsterdam
Publisher	Elsevier
Pages	221-226
Number of pages	6
ISBN (Print)	0-444-82189-9
Publication status	Published - 1995
Event	Second Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT2), 1994 - Tokyo, Japan Duration: 21 Aug 1994 → 26 Aug 1994

Publication series

Name	Studies in Surface Science and Catalysis
Volume	92
ISSN (Print)	0167-2991

Conference

Conference	Second Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT2), 1994
Country/Territory	Japan
City	Tokyo
Period	21/08/94 → 26/08/94

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Santen, van, R. A., Vissenberg, M. J., Vorbeck, G., Bont, de, P. W., Boellaard, E., Kraan, van der, A. M., & Beer, de, V. H. J. (1995). Hydrodesulfurization catalysis by small metal sulfide particles. In Y. Izumi, H. Arai, & M. Iwamoto (Eds.), Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994 (pp. 221-226). (Studies in Surface Science and Catalysis; Vol. 92). Elsevier.

Santen, van, R.A. ; Vissenberg, M.J. ; Vorbeck, G. et al. / Hydrodesulfurization catalysis by small metal sulfide particles. Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. editor / Y. Izumi ; H. Arai ; M. Iwamoto. Amsterdam : Elsevier, 1995. pp. 221-226 (Studies in Surface Science and Catalysis).

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title = "Hydrodesulfurization catalysis by small metal sulfide particles",

abstract = "Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect",

author = "\{Santen, van\}, R.A. and M.J. Vissenberg and G. Vorbeck and \{Bont, de\}, P.W. and E. Boellaard and \{Kraan, van der\}, A.M. and \{Beer, de\}, V.H.J.",

year = "1995",

language = "English",

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series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

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booktitle = "Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994",

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note = "Second Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT2), 1994 ; Conference date: 21-08-1994 Through 26-08-1994",

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Santen, van, RA, Vissenberg, MJ, Vorbeck, G, Bont, de, PW, Boellaard, E, Kraan, van der, AM & Beer, de, VHJ 1995, Hydrodesulfurization catalysis by small metal sulfide particles. in Y Izumi, H Arai & M Iwamoto (eds), Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. Studies in Surface Science and Catalysis, vol. 92, Elsevier, Amsterdam, pp. 221-226, Second Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT2), 1994, Tokyo, Japan, 21/08/94.

Hydrodesulfurization catalysis by small metal sulfide particles. / Santen, van, R.A.; Vissenberg, M.J.; Vorbeck, G. et al.
Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. ed. / Y. Izumi; H. Arai; M. Iwamoto. Amsterdam: Elsevier, 1995. p. 221-226 (Studies in Surface Science and Catalysis; Vol. 92).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Hydrodesulfurization catalysis by small metal sulfide particles

AU - Santen, van, R.A.

AU - Vissenberg, M.J.

AU - Vorbeck, G.

AU - Bont, de, P.W.

AU - Boellaard, E.

AU - Kraan, van der, A.M.

AU - Beer, de, V.H.J.

PY - 1995

Y1 - 1995

N2 - Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect

AB - Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect

M3 - Conference contribution

SN - 0-444-82189-9

T3 - Studies in Surface Science and Catalysis

SP - 221

EP - 226

BT - Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994

A2 - Izumi, Y.

A2 - Arai, H.

A2 - Iwamoto, M.

PB - Elsevier

CY - Amsterdam

T2 - Second Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT2), 1994

Y2 - 21 August 1994 through 26 August 1994

ER -

Santen, van RA, Vissenberg MJ, Vorbeck G, Bont, de PW, Boellaard E, Kraan, van der AM et al. Hydrodesulfurization catalysis by small metal sulfide particles. In Izumi Y, Arai H, Iwamoto M, editors, Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. Amsterdam: Elsevier. 1995. p. 221-226. (Studies in Surface Science and Catalysis).

Hydrodesulfurization catalysis by small metal sulfide particles

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