Hydrodesulfurization catalysis by small metal sulfide particles

R.A. Santen, van, M.J. Vissenberg, G. Vorbeck, P.W. Bont, de, E. Boellaard, A.M. Kraan, van der, V.H.J. Beer, de

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Abstract

Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect
Original languageEnglish
Title of host publicationScience and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994
EditorsY. Izumi, H. Arai, M. Iwamoto
Place of PublicationAmsterdam
PublisherElsevier
Pages221-226
ISBN (Print)0-444-82189-9
Publication statusPublished - 1995
Eventconference; Conference on Advanced Catalytic Science and Technology ; 2 (Tokyo) : 1994.08.21-26 -
Duration: 1 Jan 1995 → …

Publication series

NameStudies in Surface Science and Catalysis
Volume92
ISSN (Print)0167-2991

Conference

Conferenceconference; Conference on Advanced Catalytic Science and Technology ; 2 (Tokyo) : 1994.08.21-26
Period1/01/95 → …
OtherConference on Advanced Catalytic Science and Technology ; 2 (Tokyo) : 1994.08.21-26

Fingerprint

Hydrodesulfurization
Sulfides
Thiophenes
Catalysis
Metals
Zeolites
Catalysts
High resolution electron microscopy
Emission spectroscopy
Mossbauer spectroscopy
Carbon
Nuclear magnetic resonance
Kinetics
Temperature

Cite this

Santen, van, R. A., Vissenberg, M. J., Vorbeck, G., Bont, de, P. W., Boellaard, E., Kraan, van der, A. M., & Beer, de, V. H. J. (1995). Hydrodesulfurization catalysis by small metal sulfide particles. In Y. Izumi, H. Arai, & M. Iwamoto (Eds.), Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994 (pp. 221-226). (Studies in Surface Science and Catalysis; Vol. 92). Amsterdam: Elsevier.
Santen, van, R.A. ; Vissenberg, M.J. ; Vorbeck, G. ; Bont, de, P.W. ; Boellaard, E. ; Kraan, van der, A.M. ; Beer, de, V.H.J. / Hydrodesulfurization catalysis by small metal sulfide particles. Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. editor / Y. Izumi ; H. Arai ; M. Iwamoto. Amsterdam : Elsevier, 1995. pp. 221-226 (Studies in Surface Science and Catalysis).
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abstract = "Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect",
author = "{Santen, van}, R.A. and M.J. Vissenberg and G. Vorbeck and {Bont, de}, P.W. and E. Boellaard and {Kraan, van der}, A.M. and {Beer, de}, V.H.J.",
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Santen, van, RA, Vissenberg, MJ, Vorbeck, G, Bont, de, PW, Boellaard, E, Kraan, van der, AM & Beer, de, VHJ 1995, Hydrodesulfurization catalysis by small metal sulfide particles. in Y Izumi, H Arai & M Iwamoto (eds), Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. Studies in Surface Science and Catalysis, vol. 92, Elsevier, Amsterdam, pp. 221-226, conference; Conference on Advanced Catalytic Science and Technology ; 2 (Tokyo) : 1994.08.21-26, 1/01/95.

Hydrodesulfurization catalysis by small metal sulfide particles. / Santen, van, R.A.; Vissenberg, M.J.; Vorbeck, G.; Bont, de, P.W.; Boellaard, E.; Kraan, van der, A.M.; Beer, de, V.H.J.

Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. ed. / Y. Izumi; H. Arai; M. Iwamoto. Amsterdam : Elsevier, 1995. p. 221-226 (Studies in Surface Science and Catalysis; Vol. 92).

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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T1 - Hydrodesulfurization catalysis by small metal sulfide particles

AU - Santen, van, R.A.

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AU - Beer, de, V.H.J.

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N2 - Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect

AB - Monometallic (Mo, Co and Ni) sulfide particles dispersed in the micropores of zeolites can have a very high initial activity for the hydrodesulfurization of thiophene. Catalyst characterization, using Xe-129 NMR, HREM and Mossbauer Emission Spectroscopy (MES), shows that the location (in- or outside the zeolite pores) and size of the sulfide particles depends strongly on catalyst preparation conditions. The kinetics of thiophene HDS has been studied on metal (Mo, Co, Ph and Pt) sulfides dispersed on a carbon support. The order of thiophene in the HDS reaction appears to be a strong function of metal sulfide and temperature. The catalysts show a large compensation effect

M3 - Conference contribution

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BT - Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994

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Santen, van RA, Vissenberg MJ, Vorbeck G, Bont, de PW, Boellaard E, Kraan, van der AM et al. Hydrodesulfurization catalysis by small metal sulfide particles. In Izumi Y, Arai H, Iwamoto M, editors, Science and technology in catalysis 1994 : proceedings of the second Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, August 21-26, 1994. Amsterdam: Elsevier. 1995. p. 221-226. (Studies in Surface Science and Catalysis).