Hydrodenitrogenation of decahydroquinoline over carbon-supported transition metal sulfide catalysts

C. Sudhakar; S. Eijsbouts; V.H.J. Beer, de; R. Prins

Hydrodenitrogenation of decahydroquinoline over carbon-supported transition metal sulfide catalysts

C. Sudhakar, S. Eijsbouts, V.H.J. Beer, de, R. Prins

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

23 Citations (Scopus)

Abstract

The catalytic properties of the first, second and third row transition metal sulfides supported on activated carbon (TMS/C) were investigated for the hydrodenitrogenation of decahydroquinoline in micro- autoclaves at 50 bar total pressure and at 623 K or 653 K. Excluding vanadium sulfide, the first row TMS/C catalysts had very low activity and showed no periodic t rend. On the other hand , second and third row TMS/C catalysts were quite active and showed volcano-type periodic trends, with maxima at Rh and Ir s u lfides respectively. These periodic trends were very similar to those observed earlier for the TMS/C catalysts in the hydrodenitrogenation of quinoline and in the hydrodesulfurisation of thiophene.

Original language	English
Pages (from-to)	885-890
Number of pages	6
Journal	Bulletin des Sociétés Chimiques Belges
Volume	96
Issue number	11-12
Publication status	Published - 1987

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title = "Hydrodenitrogenation of decahydroquinoline over carbon-supported transition metal sulfide catalysts",

abstract = "The catalytic properties of the first, second and third row transition metal sulfides supported on activated carbon (TMS/C) were investigated for the hydrodenitrogenation of decahydroquinoline in micro- autoclaves at 50 bar total pressure and at 623 K or 653 K. Excluding vanadium sulfide, the first row TMS/C catalysts had very low activity and showed no periodic t rend. On the other hand , second and third row TMS/C catalysts were quite active and showed volcano-type periodic trends, with maxima at Rh and Ir s u lfides respectively. These periodic trends were very similar to those observed earlier for the TMS/C catalysts in the hydrodenitrogenation of quinoline and in the hydrodesulfurisation of thiophene.",

author = "C. Sudhakar and S. Eijsbouts and {Beer, de}, V.H.J. and R. Prins",

year = "1987",

language = "English",

volume = "96",

pages = "885--890",

journal = "Bulletin des Soci{\'e}t{\'e}s Chimiques Belges",

issn = "0037-9646",

publisher = "Wiley",

number = "11-12",

}

TY - JOUR

T1 - Hydrodenitrogenation of decahydroquinoline over carbon-supported transition metal sulfide catalysts

AU - Sudhakar, C.

AU - Eijsbouts, S.

AU - Beer, de, V.H.J.

AU - Prins, R.

PY - 1987

Y1 - 1987

N2 - The catalytic properties of the first, second and third row transition metal sulfides supported on activated carbon (TMS/C) were investigated for the hydrodenitrogenation of decahydroquinoline in micro- autoclaves at 50 bar total pressure and at 623 K or 653 K. Excluding vanadium sulfide, the first row TMS/C catalysts had very low activity and showed no periodic t rend. On the other hand , second and third row TMS/C catalysts were quite active and showed volcano-type periodic trends, with maxima at Rh and Ir s u lfides respectively. These periodic trends were very similar to those observed earlier for the TMS/C catalysts in the hydrodenitrogenation of quinoline and in the hydrodesulfurisation of thiophene.

AB - The catalytic properties of the first, second and third row transition metal sulfides supported on activated carbon (TMS/C) were investigated for the hydrodenitrogenation of decahydroquinoline in micro- autoclaves at 50 bar total pressure and at 623 K or 653 K. Excluding vanadium sulfide, the first row TMS/C catalysts had very low activity and showed no periodic t rend. On the other hand , second and third row TMS/C catalysts were quite active and showed volcano-type periodic trends, with maxima at Rh and Ir s u lfides respectively. These periodic trends were very similar to those observed earlier for the TMS/C catalysts in the hydrodenitrogenation of quinoline and in the hydrodesulfurisation of thiophene.

M3 - Article

SN - 0037-9646

VL - 96

SP - 885

EP - 890

JO - Bulletin des Sociétés Chimiques Belges

JF - Bulletin des Sociétés Chimiques Belges

IS - 11-12

ER -

Hydrodenitrogenation of decahydroquinoline over carbon-supported transition metal sulfide catalysts

Abstract

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