Homogeneous reactions in supercritical carbon dioxide using a catalyst immobilized by a microporous silica membrane

L.J.P. Broeke, van den, E.L.V. Goetheer, A.W. Verkerk, E. Wolf, de, B.J. Deelman, G. Koten, van, J.T.F. Keurentjes

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    33 Citations (Scopus)

    Abstract

    Membrane separation technology is successfully applied for the immobilization of a homogeneous catalyst (a (1H,1H,2H,2H-perfluoroalkyl)dimethylsilyl-substituted derivative of Wilkinson's catalyst) in a continuous process that uses supercritical carbon dioxide as solvent. The catalyst is separated from the products by a microporous silica membrane (see scheme).
    Original languageEnglish
    Pages (from-to)4473-4474
    JournalAngewandte Chemie - International Edition
    Volume40
    Issue number23
    DOIs
    Publication statusPublished - 2001

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