Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

L. Bini; C. Müller; J.B.M. Wilting; L. Chrzanowski, von; A.L. Spek; D. Vogt

doi:10.1021/ja074922e

Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

L. Bini, C. Müller, J.B.M. Wilting, L. Chrzanowski, von, A.L. Spek, D. Vogt

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Abstract

A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)-complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification

Original language	English
Pages (from-to)	12622-12623
Journal	Journal of the American Chemical Society
Volume	129
Issue number	42
DOIs	https://doi.org/10.1021/ja074922e
Publication status	Published - 2007

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title = "Highly selective hydrocyanation of butadiene toward 3-pentenenitrile",

abstract = "A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)-complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification",

author = "L. Bini and C. M{\"u}ller and J.B.M. Wilting and {Chrzanowski, von}, L. and A.L. Spek and D. Vogt",

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T1 - Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

AU - Bini, L.

AU - Müller, C.

AU - Wilting, J.B.M.

AU - Chrzanowski, von, L.

AU - Spek, A.L.

AU - Vogt, D.

PY - 2007

Y1 - 2007

N2 - A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)-complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification

AB - A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)-complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification

U2 - 10.1021/ja074922e

DO - 10.1021/ja074922e

M3 - Article

C2 - 17902667

SN - 0002-7863

VL - 129

SP - 12622

EP - 12623

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 42

ER -

Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

Abstract

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