Highly precise quantitative gas chromatographic method and its application to the determination of copolymerization kinetics

A.L. German; D. Heikens

doi:10.1021/ac60308a025

Highly precise quantitative gas chromatographic method and its application to the determination of copolymerization kinetics

A.L. German, D. Heikens

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A gas chromatog. anal. technique of taking samples frequently from a pressure vessel up to 20-40% conversion eliminates copolymer anal. and provides a high precision in detg. the reactivity ratios of polymg. comonomers. The monomer reactivity ratios in ethylene(I)-vinyl acetate(II) copolymn. detd. by this technique are rI = 0.743 +- 0.005 and rII = 1.515 +- 0.007

Original language	English
Pages (from-to)	1940-1944
Journal	Analytical Chemistry
Volume	43
Issue number	14
DOIs	https://doi.org/10.1021/ac60308a025
Publication status	Published - 1971

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title = "Highly precise quantitative gas chromatographic method and its application to the determination of copolymerization kinetics",

abstract = "A gas chromatog. anal. technique of taking samples frequently from a pressure vessel up to 20-40% conversion eliminates copolymer anal. and provides a high precision in detg. the reactivity ratios of polymg. comonomers. The monomer reactivity ratios in ethylene(I)-vinyl acetate(II) copolymn. detd. by this technique are rI = 0.743 +- 0.005 and rII = 1.515 +- 0.007",

author = "A.L. German and D. Heikens",

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AU - German, A.L.

AU - Heikens, D.

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AB - A gas chromatog. anal. technique of taking samples frequently from a pressure vessel up to 20-40% conversion eliminates copolymer anal. and provides a high precision in detg. the reactivity ratios of polymg. comonomers. The monomer reactivity ratios in ethylene(I)-vinyl acetate(II) copolymn. detd. by this technique are rI = 0.743 +- 0.005 and rII = 1.515 +- 0.007

U2 - 10.1021/ac60308a025

DO - 10.1021/ac60308a025

M3 - Article

SN - 0003-2700

VL - 43

SP - 1940

EP - 1944

JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 14

ER -

Highly precise quantitative gas chromatographic method and its application to the determination of copolymerization kinetics

Abstract

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