Highly anisotropic optoelectronic properties of aligned films of self-assembled platinum molecular wires

M.G. Debije; M.P. Haas, de; T.J. Savenije; J.M. Warman; M. Fontana; N. Stutzmann; W.R. Caseri; P. Smith

doi:10.1002/adma.200304603

Highly anisotropic optoelectronic properties of aligned films of self-assembled platinum molecular wires

M.G. Debije, M.P. Haas, de, T.J. Savenije, J.M. Warman, M. Fontana, N. Stutzmann, W.R. Caseri, P. Smith

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Abstract

Self-assembled columns of alternating tetrachloro- and tetraalkylaminoplatinum moieties form stable, highly oriented, optically anisotropic films on a friction-deposited polytetrafluoroethylene surface (see Figure). Charge transport in the films is rapid (mobility =¿ca. 10–2 cm2¿V–1¿s–1) and highly one-dimensional along the axis of the columns (anisotropy =¿20), further substantiating the potential application of these materials in molecular opto-electronic devices.

Original language	English
Pages (from-to)	896-899
Journal	Advanced Materials
Volume	15
Issue number	11
DOIs	https://doi.org/10.1002/adma.200304603
Publication status	Published - 2003

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Debije, M. G., Haas, de, M. P., Savenije, T. J., Warman, J. M., Fontana, M., Stutzmann, N., ... Smith, P. (2003). Highly anisotropic optoelectronic properties of aligned films of self-assembled platinum molecular wires. Advanced Materials, 15(11), 896-899. https://doi.org/10.1002/adma.200304603

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abstract = "Self-assembled columns of alternating tetrachloro- and tetraalkylaminoplatinum moieties form stable, highly oriented, optically anisotropic films on a friction-deposited polytetrafluoroethylene surface (see Figure). Charge transport in the films is rapid (mobility =¿ca. 10–2 cm2¿V–1¿s–1) and highly one-dimensional along the axis of the columns (anisotropy =¿20), further substantiating the potential application of these materials in molecular opto-electronic devices.",

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AU - Debije, M.G.

AU - Haas, de, M.P.

AU - Savenije, T.J.

AU - Warman, J.M.

AU - Fontana, M.

AU - Stutzmann, N.

AU - Caseri, W.R.

AU - Smith, P.

PY - 2003

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N2 - Self-assembled columns of alternating tetrachloro- and tetraalkylaminoplatinum moieties form stable, highly oriented, optically anisotropic films on a friction-deposited polytetrafluoroethylene surface (see Figure). Charge transport in the films is rapid (mobility =¿ca. 10–2 cm2¿V–1¿s–1) and highly one-dimensional along the axis of the columns (anisotropy =¿20), further substantiating the potential application of these materials in molecular opto-electronic devices.

AB - Self-assembled columns of alternating tetrachloro- and tetraalkylaminoplatinum moieties form stable, highly oriented, optically anisotropic films on a friction-deposited polytetrafluoroethylene surface (see Figure). Charge transport in the films is rapid (mobility =¿ca. 10–2 cm2¿V–1¿s–1) and highly one-dimensional along the axis of the columns (anisotropy =¿20), further substantiating the potential application of these materials in molecular opto-electronic devices.

U2 - 10.1002/adma.200304603

DO - 10.1002/adma.200304603

M3 - Article

VL - 15

SP - 896

EP - 899

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 11

ER -

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10.1002/adma.200304603