High-throughput investigation of polymerization kinetics by online monitoring of GPC and GC

R. Hoogenboom; M.W.M. Fijten; C.H. Abeln; U.S. Schubert

doi:10.1002/marc.200300218

High-throughput investigation of polymerization kinetics by online monitoring of GPC and GC

R. Hoogenboom, M.W.M. Fijten, C.H. Abeln, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

51 Citations (Scopus)

Abstract

Gel permeation chromatography (GPC) and gas chromatography (GC) were successfully introduced into a high-throughput workflow. The feasibility and limitations of online GPC with a high-speed column was evaluated by measuring polystyrene standards and comparison of the results with regular offline GPC measurements. The reliability of the online GC characterization was investigated by monitoring the cationic ring-opening-polymerization of 2-ethyl-2-oxazoline, whose polymerization kinetics were determined by both online and offline GC.

Original language	English
Pages (from-to)	237-242
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	1
DOIs	https://doi.org/10.1002/marc.200300218
Publication status	Published - 2004

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10.1002/marc.200300218

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abstract = "Gel permeation chromatography (GPC) and gas chromatography (GC) were successfully introduced into a high-throughput workflow. The feasibility and limitations of online GPC with a high-speed column was evaluated by measuring polystyrene standards and comparison of the results with regular offline GPC measurements. The reliability of the online GC characterization was investigated by monitoring the cationic ring-opening-polymerization of 2-ethyl-2-oxazoline, whose polymerization kinetics were determined by both online and offline GC.",

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AU - Hoogenboom, R.

AU - Fijten, M.W.M.

AU - Abeln, C.H.

AU - Schubert, U.S.

PY - 2004

Y1 - 2004

N2 - Gel permeation chromatography (GPC) and gas chromatography (GC) were successfully introduced into a high-throughput workflow. The feasibility and limitations of online GPC with a high-speed column was evaluated by measuring polystyrene standards and comparison of the results with regular offline GPC measurements. The reliability of the online GC characterization was investigated by monitoring the cationic ring-opening-polymerization of 2-ethyl-2-oxazoline, whose polymerization kinetics were determined by both online and offline GC.

AB - Gel permeation chromatography (GPC) and gas chromatography (GC) were successfully introduced into a high-throughput workflow. The feasibility and limitations of online GPC with a high-speed column was evaluated by measuring polystyrene standards and comparison of the results with regular offline GPC measurements. The reliability of the online GC characterization was investigated by monitoring the cationic ring-opening-polymerization of 2-ethyl-2-oxazoline, whose polymerization kinetics were determined by both online and offline GC.

U2 - 10.1002/marc.200300218

DO - 10.1002/marc.200300218

M3 - Article

SN - 1022-1336

VL - 25

SP - 237

EP - 242

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 1

ER -

High-throughput investigation of polymerization kinetics by online monitoring of GPC and GC

Abstract

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