High-performance all-polymer solar cells based on fluorinated naphthalene diimide acceptor polymers with fine-tuned crystallinity and enhanced dielectric constants

X. Xu, Z. Li, J. Wang, B. Lin, W. Ma, Y. Xia, M.R. Andersson, R.A.J. Janssen, E. Wang

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Abstract

Growing interests have been devoted to the synthesis of polymer acceptors as alternatives to fullerene derivatives to realize high-performance and stable all-polymer solar cells (all-PSCs). So far, one of the key factors that limit the performance of all-PSCs is low photocurrent density (normally < 14 mA/cm2). One potential solution is to improve the dielectric constants (εr) of polymer:polymer blends, which tend to reduce the binding energy of excitons, thus boosting the exciton dissociation efficiencies. Nevertheless, the correlation between εr and photovoltaic performance has been rarely investigated for all-PSCs. In this work, five fluorinated naphthalene diimide (NDI)-based acceptor polymers, with different content of fluorine were synthesized. The incorporation of fluorine increased the εr of the acceptor polymers and blend films, which improved the charge generation and overall photocurrent of the all-PSCs. As a result, the PTB7-Th:PNDI-FT10 all-PSC attained a high power conversion efficiency (PCE) of 7.3% with a photocurrent density of 14.7 mA/cm2, which surpassed the values reported for the all-PSC based on the non-fluorinated acceptor PNDI-T10. Interestingly, similarly high photovoltaic performance was maintained regardless of a large variation of donor:acceptor ratios, which revealed the good morphological tolerance and the potential for robust production capability of all-PSCs.

Original languageEnglish
Pages (from-to)368-379
Number of pages12
JournalNano Energy
Volume45
DOIs
Publication statusPublished - 1 Mar 2018

Fingerprint

Naphthalene
Polymers
Permittivity
Photocurrents
Fluorine
Excitons
Fullerenes
Polymer blends
Polymer solar cells
naphthalenediimide
Binding energy
Conversion efficiency
Derivatives

Keywords

  • Acceptor polymers
  • All-polymer solar cells
  • Binding energy
  • Dielectric constants
  • Organic photovoltaics

Cite this

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title = "High-performance all-polymer solar cells based on fluorinated naphthalene diimide acceptor polymers with fine-tuned crystallinity and enhanced dielectric constants",
abstract = "Growing interests have been devoted to the synthesis of polymer acceptors as alternatives to fullerene derivatives to realize high-performance and stable all-polymer solar cells (all-PSCs). So far, one of the key factors that limit the performance of all-PSCs is low photocurrent density (normally < 14 mA/cm2). One potential solution is to improve the dielectric constants (εr) of polymer:polymer blends, which tend to reduce the binding energy of excitons, thus boosting the exciton dissociation efficiencies. Nevertheless, the correlation between εr and photovoltaic performance has been rarely investigated for all-PSCs. In this work, five fluorinated naphthalene diimide (NDI)-based acceptor polymers, with different content of fluorine were synthesized. The incorporation of fluorine increased the εr of the acceptor polymers and blend films, which improved the charge generation and overall photocurrent of the all-PSCs. As a result, the PTB7-Th:PNDI-FT10 all-PSC attained a high power conversion efficiency (PCE) of 7.3{\%} with a photocurrent density of 14.7 mA/cm2, which surpassed the values reported for the all-PSC based on the non-fluorinated acceptor PNDI-T10. Interestingly, similarly high photovoltaic performance was maintained regardless of a large variation of donor:acceptor ratios, which revealed the good morphological tolerance and the potential for robust production capability of all-PSCs.",
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High-performance all-polymer solar cells based on fluorinated naphthalene diimide acceptor polymers with fine-tuned crystallinity and enhanced dielectric constants. / Xu, X.; Li, Z.; Wang, J.; Lin, B.; Ma, W.; Xia, Y.; Andersson, M.R.; Janssen, R.A.J.; Wang, E.

In: Nano Energy, Vol. 45, 01.03.2018, p. 368-379.

Research output: Contribution to journalArticleAcademicpeer-review

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T1 - High-performance all-polymer solar cells based on fluorinated naphthalene diimide acceptor polymers with fine-tuned crystallinity and enhanced dielectric constants

AU - Xu, X.

AU - Li, Z.

AU - Wang, J.

AU - Lin, B.

AU - Ma, W.

AU - Xia, Y.

AU - Andersson, M.R.

AU - Janssen, R.A.J.

AU - Wang, E.

PY - 2018/3/1

Y1 - 2018/3/1

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AB - Growing interests have been devoted to the synthesis of polymer acceptors as alternatives to fullerene derivatives to realize high-performance and stable all-polymer solar cells (all-PSCs). So far, one of the key factors that limit the performance of all-PSCs is low photocurrent density (normally < 14 mA/cm2). One potential solution is to improve the dielectric constants (εr) of polymer:polymer blends, which tend to reduce the binding energy of excitons, thus boosting the exciton dissociation efficiencies. Nevertheless, the correlation between εr and photovoltaic performance has been rarely investigated for all-PSCs. In this work, five fluorinated naphthalene diimide (NDI)-based acceptor polymers, with different content of fluorine were synthesized. The incorporation of fluorine increased the εr of the acceptor polymers and blend films, which improved the charge generation and overall photocurrent of the all-PSCs. As a result, the PTB7-Th:PNDI-FT10 all-PSC attained a high power conversion efficiency (PCE) of 7.3% with a photocurrent density of 14.7 mA/cm2, which surpassed the values reported for the all-PSC based on the non-fluorinated acceptor PNDI-T10. Interestingly, similarly high photovoltaic performance was maintained regardless of a large variation of donor:acceptor ratios, which revealed the good morphological tolerance and the potential for robust production capability of all-PSCs.

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KW - All-polymer solar cells

KW - Binding energy

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