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Group-type identification of oil samples using comprehensive two-dimensional gas chromatography coupled to a time-of-flight mass spectrometer (GCxGC-TOF)

  • M.M. Deursen, van
  • , J. Beens
  • , J.C. Reijenga
  • , P.J.L. Lipman
  • , C.A.M.G. Cramers
  • , J. Blomberg

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

In this work a comprehensive two-dimensional system (GC6GC) was coupled to a time-of-flight mass spectrometer (TOF/MS) for the analysis of oil samples. Group-types like the alkanes and saturated cyclic compounds (naphthenes), which are present in oil, are shown separately by selecting their unique masses. On selecting appropriate ion fragments, this method also permits the determination of sulfurand oxygen-containing species in oil. Former results obtained by FID detection could be confirmed. After proper selection of unique ions in GC6GC-TOF both selectivity and sensitivity increase.
Original languageEnglish
Pages (from-to)507-510
Number of pages4
JournalJournal of High Resolution Chromatography
Volume23
Issue number7-8
DOIs
Publication statusPublished - 2000

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