Grid forming metal coordinating macroligands: synthesis and complexation

R. Hoogenboom; J. Huskens; D. Wouters; U.S. Schubert

doi:10.1021/bk-2006-0928.ch005

Grid forming metal coordinating macroligands: synthesis and complexation

R. Hoogenboom, J. Huskens, D. Wouters, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

6 Citations (Scopus)

1 Downloads (Pure)

Abstract

The synthesis of poly(L-lactide) bispyridylpyridazine macroligands from a hydroxyl functionalized ligand by controlled ring-opening polymerization is described. The resulting macroligands were characterized by 1H-NMR spectroscopy, GPC and MALDI-TOF MS. The metal coordination of those macroligands with copper(I) resulting in polymeric [2x2] metal grids was investigated by UV-vis titration studies. In addition, the complexation behavior obtained from these experiments was modeled in order to explore the complexation parameters and the corresponding mechanism

Original language	English
Title of host publication	Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]
Editors	U.S. Schubert
Place of Publication	Washington, DC
Publisher	American Chemical Society
Pages	62-71
ISBN (Print)	8412-3929-0
DOIs	https://doi.org/10.1021/bk-2006-0928.ch005
Publication status	Published - 2006
Event	Metal-Containing and Metallosupramolecular Polymers and Materials - Anaheim, United States Duration: 28 Mar 2004 → 1 Apr 2004

Publication series

Name	ACS Symposium Series
Volume	928
ISSN (Print)	0097-6156

Conference

Conference	Metal-Containing and Metallosupramolecular Polymers and Materials
Country/Territory	United States
City	Anaheim
Period	28/03/04 → 1/04/04
Other	Symposium in spring 2004 during the 227th ACS National Meeting

Access to Document

10.1021/bk-2006-0928.ch005

Cite this

Hoogenboom, R., Huskens, J., Wouters, D., & Schubert, U. S. (2006). Grid forming metal coordinating macroligands: synthesis and complexation. In U. S. Schubert (Ed.), Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California] (pp. 62-71). (ACS Symposium Series; Vol. 928). American Chemical Society. https://doi.org/10.1021/bk-2006-0928.ch005

Hoogenboom, R. ; Huskens, J. ; Wouters, D. et al. / Grid forming metal coordinating macroligands: synthesis and complexation. Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]. editor / U.S. Schubert. Washington, DC : American Chemical Society, 2006. pp. 62-71 (ACS Symposium Series).

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title = "Grid forming metal coordinating macroligands: synthesis and complexation",

abstract = "The synthesis of poly(L-lactide) bispyridylpyridazine macroligands from a hydroxyl functionalized ligand by controlled ring-opening polymerization is described. The resulting macroligands were characterized by 1H-NMR spectroscopy, GPC and MALDI-TOF MS. The metal coordination of those macroligands with copper(I) resulting in polymeric [2x2] metal grids was investigated by UV-vis titration studies. In addition, the complexation behavior obtained from these experiments was modeled in order to explore the complexation parameters and the corresponding mechanism",

author = "R. Hoogenboom and J. Huskens and D. Wouters and U.S. Schubert",

year = "2006",

doi = "10.1021/bk-2006-0928.ch005",

language = "English",

isbn = "8412-3929-0",

series = "ACS Symposium Series",

publisher = "American Chemical Society",

pages = "62--71",

editor = "U.S. Schubert",

booktitle = "Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]",

address = "United States",

note = "Metal-Containing and Metallosupramolecular Polymers and Materials ; Conference date: 28-03-2004 Through 01-04-2004",

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Hoogenboom, R, Huskens, J, Wouters, D & Schubert, US 2006, Grid forming metal coordinating macroligands: synthesis and complexation. in US Schubert (ed.), Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]. ACS Symposium Series, vol. 928, American Chemical Society, Washington, DC, pp. 62-71, Metal-Containing and Metallosupramolecular Polymers and Materials, Anaheim, California, United States, 28/03/04. https://doi.org/10.1021/bk-2006-0928.ch005

Grid forming metal coordinating macroligands: synthesis and complexation. / Hoogenboom, R.; Huskens, J.; Wouters, D. et al.
Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]. ed. / U.S. Schubert. Washington, DC: American Chemical Society, 2006. p. 62-71 (ACS Symposium Series; Vol. 928).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Grid forming metal coordinating macroligands: synthesis and complexation

AU - Hoogenboom, R.

AU - Huskens, J.

AU - Wouters, D.

AU - Schubert, U.S.

PY - 2006

Y1 - 2006

N2 - The synthesis of poly(L-lactide) bispyridylpyridazine macroligands from a hydroxyl functionalized ligand by controlled ring-opening polymerization is described. The resulting macroligands were characterized by 1H-NMR spectroscopy, GPC and MALDI-TOF MS. The metal coordination of those macroligands with copper(I) resulting in polymeric [2x2] metal grids was investigated by UV-vis titration studies. In addition, the complexation behavior obtained from these experiments was modeled in order to explore the complexation parameters and the corresponding mechanism

AB - The synthesis of poly(L-lactide) bispyridylpyridazine macroligands from a hydroxyl functionalized ligand by controlled ring-opening polymerization is described. The resulting macroligands were characterized by 1H-NMR spectroscopy, GPC and MALDI-TOF MS. The metal coordination of those macroligands with copper(I) resulting in polymeric [2x2] metal grids was investigated by UV-vis titration studies. In addition, the complexation behavior obtained from these experiments was modeled in order to explore the complexation parameters and the corresponding mechanism

U2 - 10.1021/bk-2006-0928.ch005

DO - 10.1021/bk-2006-0928.ch005

M3 - Conference contribution

SN - 8412-3929-0

T3 - ACS Symposium Series

SP - 62

EP - 71

BT - Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]

A2 - Schubert, U.S.

PB - American Chemical Society

CY - Washington, DC

T2 - Metal-Containing and Metallosupramolecular Polymers and Materials

Y2 - 28 March 2004 through 1 April 2004

ER -

Hoogenboom R, Huskens J, Wouters D, Schubert US. Grid forming metal coordinating macroligands: synthesis and complexation. In Schubert US, editor, Metal-containing and metallosupramolecular polymers and materials : [American Chemical Society (ACS) symposium in spring 2004 during the ACS national meeting in Anaheim, California]. Washington, DC: American Chemical Society. 2006. p. 62-71. (ACS Symposium Series). doi: 10.1021/bk-2006-0928.ch005

Grid forming metal coordinating macroligands: synthesis and complexation

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