Gold nanoparticle catalysts for the hydro-epoxidation of propene: an in-situ XANES and catalytic study into the adsorption of propene on gold

T.A. Nijhuis, E. Sacaliuc, A.M.J. Eerden, van der, B.M. Weckhuysen, J.C. Schouten

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

Abstract

Gold nanoparticle catalysts for the direct epoxidation of propylene were studied. The hydrogen oxidation over gold was used as a probe reaction for the catalytic activity of the gold nanoparticles. Propylene adsorbed strongly on gold under reaction conditions typical for the hydro-epoxidation of propylene. Under propylene hydro-epoxidation reaction conditions, propylene was absorbing on gold nanoparticles. Propylene adsorption decreased the hydrogen oxidation rate and interacted with surface gold atoms. This is an abstract of a paper presented at the AIChE Spring National Meeting (New Orleans, LA 4/6-10/2008).
Original languageEnglish
Title of host publicationGreen Chemical Reaction Engineering for a Sustainable Future. Proceedings of the 20st Int. Symp. on Chemical Reaction Engineering (ISCRE-20), 7-10 September 2008, Kyoto, Japan
EditorsH. Komiyama
PublisherSociety of Chemical Engineers, Japan
Pages440-441
Publication statusPublished - 2008

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    Nijhuis, T. A., Sacaliuc, E., Eerden, van der, A. M. J., Weckhuysen, B. M., & Schouten, J. C. (2008). Gold nanoparticle catalysts for the hydro-epoxidation of propene: an in-situ XANES and catalytic study into the adsorption of propene on gold. In H. Komiyama (Ed.), Green Chemical Reaction Engineering for a Sustainable Future. Proceedings of the 20st Int. Symp. on Chemical Reaction Engineering (ISCRE-20), 7-10 September 2008, Kyoto, Japan (pp. 440-441). Society of Chemical Engineers, Japan.