Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 2530-2534 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 2010 |
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Glucose activation by transient Cr2+ dimers. / Pidko, E.A.; Degirmenci, V.; Santen, van, R.A.; Hensen, E.J.M.
In: Angewandte Chemie - International Edition, Vol. 49, No. 14, 2010, p. 2530-2534.Research output: Contribution to journal › Article › Academic › peer-review
TY - JOUR
T1 - Glucose activation by transient Cr2+ dimers
AU - Pidko, E.A.
AU - Degirmenci, V.
AU - Santen, van, R.A.
AU - Hensen, E.J.M.
PY - 2010
Y1 - 2010
N2 - Figure Presented] Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.© 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
AB - Figure Presented] Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.© 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
U2 - 10.1002/anie.201000250
DO - 10.1002/anie.201000250
M3 - Article
C2 - 20232433
VL - 49
SP - 2530
EP - 2534
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 0570-0833
IS - 14
ER -