Glucose activation by transient Cr2+ dimers

E.A. Pidko; V. Degirmenci; R.A. Santen, van; E.J.M. Hensen

doi:10.1002/anie.201000250

Glucose activation by transient Cr2+ dimers

E.A. Pidko, V. Degirmenci, R.A. Santen, van, E.J.M. Hensen

www.catalysis.nl

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Abstract

Figure Presented] Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.© 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	2530-2534
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	14
DOIs	https://doi.org/10.1002/anie.201000250
Publication status	Published - 2010

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abstract = "Figure Presented] Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.{\textcopyright} 2010 Wiley-VCH Verlag GmbH & Co. KGaA.",

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AU - Degirmenci, V.

AU - Santen, van, R.A.

AU - Hensen, E.J.M.

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N2 - Figure Presented] Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.© 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Figure Presented] Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.© 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

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DO - 10.1002/anie.201000250

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 0570-0833

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Glucose activation by transient Cr2+ dimers

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