Global kinetics of the alkaline oxidative degradations of lactose

H.E.J. Hendriks; B.F.M. Kuster; G.B.M.M. Marin

doi:10.1016/0304-5102(94)00122-7

Global kinetics of the alkaline oxidative degradations of lactose

H.E.J. Hendriks, B.F.M. Kuster, G.B.M.M. Marin

Chemical Reactor Engineering

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The kinetics of the \"classical\" and the anthraquinone-2-sulfonate (AMS) catalyzed alk. oxidative degrdn. of lactose and related carbohydrates have been investigated. Regression anal. of the exptl. data, using a multi-response Marquardt algorithm, allowed the exptl. data to be described adequately by a reaction sequence consisting of different oxidn. pathways starting from the sugar enediolates and having the formation of the latter as the common, most important, rate-detg. step

Original language	English
Pages (from-to)	317-335
Journal	Journal of Molecular Catalysis
Volume	93
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(94)00122-7
Publication status	Published - 1994

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N2 - The kinetics of the \"classical\" and the anthraquinone-2-sulfonate (AMS) catalyzed alk. oxidative degrdn. of lactose and related carbohydrates have been investigated. Regression anal. of the exptl. data, using a multi-response Marquardt algorithm, allowed the exptl. data to be described adequately by a reaction sequence consisting of different oxidn. pathways starting from the sugar enediolates and having the formation of the latter as the common, most important, rate-detg. step

AB - The kinetics of the \"classical\" and the anthraquinone-2-sulfonate (AMS) catalyzed alk. oxidative degrdn. of lactose and related carbohydrates have been investigated. Regression anal. of the exptl. data, using a multi-response Marquardt algorithm, allowed the exptl. data to be described adequately by a reaction sequence consisting of different oxidn. pathways starting from the sugar enediolates and having the formation of the latter as the common, most important, rate-detg. step

U2 - 10.1016/0304-5102(94)00122-7

DO - 10.1016/0304-5102(94)00122-7

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EP - 335

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

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