Functionalized polymers with metal complexing segments : a simple and high-yield entry towards 2,2':6',2''-terpyridine-based oligomers

U.S. Schubert; O. Hien; C. Eschbaumer

doi:10.1002/1521-3927(20001101)21:16<1156::AID-MARC1156>3.0.CO;2-O

Functionalized polymers with metal complexing segments : a simple and high-yield entry towards 2,2':6',2''-terpyridine-based oligomers

U.S. Schubert
, O. Hien
, C. Eschbaumer

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

93 Citations (Scopus)

2 Downloads (Pure)

Abstract

Williamson type ether reactions were utilized for a high yield reaction of 4-chloro-2,2:6,2-terpyridine with ,-dihydroxy-functionalized poly(ethylene oxide) and poly(oxytetramethylene)s to obtain bis(terpyridine)-terminated telechelics. The completeness of the functionalization was proven by NMR spectroscopy, GPC and MALDI-TOF-MS investigations. The addition of transition metal ions resulted in a polyaddition polymerization leading to the formation of extended metallo-supramolecular polymers, as proven by UV/VIS spectroscopy titration experiments.

Original language	English
Pages (from-to)	1156-1161
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	21
Issue number	16
DOIs	https://doi.org/10.1002/1521-3927(20001101)21:16<1156::AID-MARC1156>3.0.CO;2-O
Publication status	Published - 2000

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title = "Functionalized polymers with metal complexing segments : a simple and high-yield entry towards 2,2':6',2''-terpyridine-based oligomers",

abstract = "Williamson type ether reactions were utilized for a high yield reaction of 4-chloro-2,2:6,2-terpyridine with ,-dihydroxy-functionalized poly(ethylene oxide) and poly(oxytetramethylene)s to obtain bis(terpyridine)-terminated telechelics. The completeness of the functionalization was proven by NMR spectroscopy, GPC and MALDI-TOF-MS investigations. The addition of transition metal ions resulted in a polyaddition polymerization leading to the formation of extended metallo-supramolecular polymers, as proven by UV/VIS spectroscopy titration experiments.",

author = "U.S. Schubert and O. Hien and C. Eschbaumer",

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doi = "10.1002/1521-3927(20001101)21:16<1156::AID-MARC1156>3.0.CO;2-O",

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T1 - Functionalized polymers with metal complexing segments : a simple and high-yield entry towards 2,2':6',2''-terpyridine-based oligomers

AU - Schubert, U.S.

AU - Hien, O.

AU - Eschbaumer, C.

PY - 2000

Y1 - 2000

N2 - Williamson type ether reactions were utilized for a high yield reaction of 4-chloro-2,2:6,2-terpyridine with ,-dihydroxy-functionalized poly(ethylene oxide) and poly(oxytetramethylene)s to obtain bis(terpyridine)-terminated telechelics. The completeness of the functionalization was proven by NMR spectroscopy, GPC and MALDI-TOF-MS investigations. The addition of transition metal ions resulted in a polyaddition polymerization leading to the formation of extended metallo-supramolecular polymers, as proven by UV/VIS spectroscopy titration experiments.

AB - Williamson type ether reactions were utilized for a high yield reaction of 4-chloro-2,2:6,2-terpyridine with ,-dihydroxy-functionalized poly(ethylene oxide) and poly(oxytetramethylene)s to obtain bis(terpyridine)-terminated telechelics. The completeness of the functionalization was proven by NMR spectroscopy, GPC and MALDI-TOF-MS investigations. The addition of transition metal ions resulted in a polyaddition polymerization leading to the formation of extended metallo-supramolecular polymers, as proven by UV/VIS spectroscopy titration experiments.

U2 - 10.1002/1521-3927(20001101)21:16<1156::AID-MARC1156>3.0.CO;2-O

DO - 10.1002/1521-3927(20001101)21:16<1156::AID-MARC1156>3.0.CO;2-O

M3 - Article

SN - 1022-1336

VL - 21

SP - 1156

EP - 1161

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 16

ER -

Functionalized polymers with metal complexing segments : a simple and high-yield entry towards 2,2':6',2''-terpyridine-based oligomers

Abstract

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