Free radical and thermal curing of terpyridine-modified terpolymers

H. Hofmeier; A. El-Ghayoury; U.S. Schubert

doi:10.1002/pola.20253

Free radical and thermal curing of terpyridine-modified terpolymers

H. Hofmeier, A. El-Ghayoury, U.S. Schubert

Research output: Contribution to journal › Article › Academic › peer-review

10 Citations (Scopus)

Abstract

Terpolymers bearing terpyridine as well as (meth)acrylates as free radical curable groups (UV-curing) or hydroxyl groups (thermal curing with bis-isocyanates) were synthesized and characterized using 1H NMR, IR and UV-vis spectroscopy as well as GPC. Subsequently, the ability of covalent crosslinking via the UV-initiated polymerization of the acrylate groups was investigated. Moreover, the thermal covalent crosslinking via the reaction of hydroxyl functionalized terpolymer and bis-isocyanate compounds could be successfully achieved.

Original language	English
Pages (from-to)	4028-4035
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	42
Issue number	16
DOIs	https://doi.org/10.1002/pola.20253
Publication status	Published - 2004

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title = "Free radical and thermal curing of terpyridine-modified terpolymers",

abstract = "Terpolymers bearing terpyridine as well as (meth)acrylates as free radical curable groups (UV-curing) or hydroxyl groups (thermal curing with bis-isocyanates) were synthesized and characterized using 1H NMR, IR and UV-vis spectroscopy as well as GPC. Subsequently, the ability of covalent crosslinking via the UV-initiated polymerization of the acrylate groups was investigated. Moreover, the thermal covalent crosslinking via the reaction of hydroxyl functionalized terpolymer and bis-isocyanate compounds could be successfully achieved.",

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AU - Hofmeier, H.

AU - El-Ghayoury, A.

AU - Schubert, U.S.

PY - 2004

Y1 - 2004

N2 - Terpolymers bearing terpyridine as well as (meth)acrylates as free radical curable groups (UV-curing) or hydroxyl groups (thermal curing with bis-isocyanates) were synthesized and characterized using 1H NMR, IR and UV-vis spectroscopy as well as GPC. Subsequently, the ability of covalent crosslinking via the UV-initiated polymerization of the acrylate groups was investigated. Moreover, the thermal covalent crosslinking via the reaction of hydroxyl functionalized terpolymer and bis-isocyanate compounds could be successfully achieved.

AB - Terpolymers bearing terpyridine as well as (meth)acrylates as free radical curable groups (UV-curing) or hydroxyl groups (thermal curing with bis-isocyanates) were synthesized and characterized using 1H NMR, IR and UV-vis spectroscopy as well as GPC. Subsequently, the ability of covalent crosslinking via the UV-initiated polymerization of the acrylate groups was investigated. Moreover, the thermal covalent crosslinking via the reaction of hydroxyl functionalized terpolymer and bis-isocyanate compounds could be successfully achieved.

U2 - 10.1002/pola.20253

DO - 10.1002/pola.20253

M3 - Article

SN - 0887-624X

VL - 42

SP - 4028

EP - 4035

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 16

ER -

Free radical and thermal curing of terpyridine-modified terpolymers

Abstract

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