Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

P. Schipper, W.A.M. Castenmiller, J.W. Haan, de, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

3 Citations (Scopus)
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Abstract

While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.
Original languageEnglish
Pages (from-to)574-575
JournalJournal of the Chemical Society, Chemical Communications
Issue number16
DOIs
Publication statusPublished - 1973

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