Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

P. Schipper; W.A.M. Castenmiller; J.W. Haan, de; H.M. Buck

doi:10.1039/c39730000574

Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

P. Schipper, W.A.M. Castenmiller, J.W. Haan, de, H.M. Buck

Chemical Engineering and Chemistry

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Abstract

While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.

Original language	English
Pages (from-to)	574-575
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/c39730000574
Publication status	Published - 1973

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title = "Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication",

abstract = "While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.",

author = "P. Schipper and W.A.M. Castenmiller and {Haan, de}, J.W. and H.M. Buck",

year = "1973",

doi = "10.1039/c39730000574",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

AU - Schipper, P.

AU - Castenmiller, W.A.M.

AU - Haan, de, J.W.

AU - Buck, H.M.

PY - 1973

Y1 - 1973

N2 - While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.

AB - While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.

U2 - 10.1039/c39730000574

DO - 10.1039/c39730000574

M3 - Article

SN - 0022-4936

SP - 574

EP - 575

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

Abstract

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