Formation of poly(2,5-dibutoxy-1,4-phenylenevinylene) at room temperature in CHCl3 catalyzed by CHCl3 photoproducts

A. Delmotte; M. Biesemans; H. Rahier; M. Gielen; E.W. Meijer

doi:10.1016/0379-6779(93)91141-N

Formation of poly(2,5-dibutoxy-1,4-phenylenevinylene) at room temperature in CHCl3 catalyzed by CHCl3 photoproducts

A. Delmotte
, M. Biesemans
, H. Rahier
, M. Gielen
, E.W. Meijer

Macromolecular and Organic Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

17 Citations (Scopus)

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Abstract

A convenient, mild prepn. of poly(2,5-dibutoxy-1,4-phenylenevinylene) (I) using a modified precursor route is reported. The conversion of the methoxy pendent precursor polymer into its conjugated form is performed in chloroform by the elimination of methanol at room temp., yielding I as a red soln. The elimination is catalyzed by the acid photoproducts of chloroform. [on SciFinder (R)]

Original language	English
Pages (from-to)	325-334
Number of pages	14
Journal	Synthetic Metals
Volume	58
Issue number	3
DOIs	https://doi.org/10.1016/0379-6779(93)91141-N
Publication status	Published - 1993

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title = "Formation of poly(2,5-dibutoxy-1,4-phenylenevinylene) at room temperature in CHCl3 catalyzed by CHCl3 photoproducts",

abstract = "A convenient, mild prepn. of poly(2,5-dibutoxy-1,4-phenylenevinylene) (I) using a modified precursor route is reported. The conversion of the methoxy pendent precursor polymer into its conjugated form is performed in chloroform by the elimination of methanol at room temp., yielding I as a red soln. The elimination is catalyzed by the acid photoproducts of chloroform. [on SciFinder (R)]",

author = "A. Delmotte and M. Biesemans and H. Rahier and M. Gielen and E.W. Meijer",

year = "1993",

doi = "10.1016/0379-6779(93)91141-N",

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pages = "325--334",

journal = "Synthetic Metals",

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T1 - Formation of poly(2,5-dibutoxy-1,4-phenylenevinylene) at room temperature in CHCl3 catalyzed by CHCl3 photoproducts

AU - Delmotte, A.

AU - Biesemans, M.

AU - Rahier, H.

AU - Gielen, M.

AU - Meijer, E.W.

PY - 1993

Y1 - 1993

N2 - A convenient, mild prepn. of poly(2,5-dibutoxy-1,4-phenylenevinylene) (I) using a modified precursor route is reported. The conversion of the methoxy pendent precursor polymer into its conjugated form is performed in chloroform by the elimination of methanol at room temp., yielding I as a red soln. The elimination is catalyzed by the acid photoproducts of chloroform. [on SciFinder (R)]

AB - A convenient, mild prepn. of poly(2,5-dibutoxy-1,4-phenylenevinylene) (I) using a modified precursor route is reported. The conversion of the methoxy pendent precursor polymer into its conjugated form is performed in chloroform by the elimination of methanol at room temp., yielding I as a red soln. The elimination is catalyzed by the acid photoproducts of chloroform. [on SciFinder (R)]

U2 - 10.1016/0379-6779(93)91141-N

DO - 10.1016/0379-6779(93)91141-N

M3 - Article

SN - 0379-6779

VL - 58

SP - 325

EP - 334

JO - Synthetic Metals

JF - Synthetic Metals

IS - 3

ER -

Formation of poly(2,5-dibutoxy-1,4-phenylenevinylene) at room temperature in CHCl3 catalyzed by CHCl3 photoproducts

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