Formation of open anions from dihydro-oxepin

H. Kloosterziel; J.A.A. Drunen, van

doi:10.1002/recl.19700890613

Formation of open anions from dihydro-oxepin

H. Kloosterziel, J.A.A. Drunen, van

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

12 Citations (Scopus)

Abstract

Reaction of 2,3-dihydrooxepin (I) with KNH2 in liq. NH3 yields, as revealed by NMR spectroscopy, the trans-2,cis-3,trans-4,cis-5-7-oxaheptatrienyl anion, which is of fair configurational stability. The barriers for rotation in the oxaheptatrienyl anion are discussed. [on SciFinder (R)]

Original language	English
Pages (from-to)	667-672
Journal	Recueil des Travaux Chimiques des Pays-Bas
Volume	89
Issue number	6
DOIs	https://doi.org/10.1002/recl.19700890613
Publication status	Published - 1970

Access to Document

10.1002/recl.19700890613

Cite this

@article{76ab441c0c3d424c925cc0d8b002c66c,

title = "Formation of open anions from dihydro-oxepin",

abstract = "Reaction of 2,3-dihydrooxepin (I) with KNH2 in liq. NH3 yields, as revealed by NMR spectroscopy, the trans-2,cis-3,trans-4,cis-5-7-oxaheptatrienyl anion, which is of fair configurational stability. The barriers for rotation in the oxaheptatrienyl anion are discussed. [on SciFinder (R)]",

author = "H. Kloosterziel and {Drunen, van}, J.A.A.",

year = "1970",

doi = "10.1002/recl.19700890613",

language = "English",

volume = "89",

pages = "667--672",

journal = "Recueil des Travaux Chimiques des Pays-Bas",

issn = "0165-0513",

publisher = "Royal Netherlands Chemical Society",

number = "6",

}

TY - JOUR

T1 - Formation of open anions from dihydro-oxepin

AU - Kloosterziel, H.

AU - Drunen, van, J.A.A.

PY - 1970

Y1 - 1970

N2 - Reaction of 2,3-dihydrooxepin (I) with KNH2 in liq. NH3 yields, as revealed by NMR spectroscopy, the trans-2,cis-3,trans-4,cis-5-7-oxaheptatrienyl anion, which is of fair configurational stability. The barriers for rotation in the oxaheptatrienyl anion are discussed. [on SciFinder (R)]

AB - Reaction of 2,3-dihydrooxepin (I) with KNH2 in liq. NH3 yields, as revealed by NMR spectroscopy, the trans-2,cis-3,trans-4,cis-5-7-oxaheptatrienyl anion, which is of fair configurational stability. The barriers for rotation in the oxaheptatrienyl anion are discussed. [on SciFinder (R)]

U2 - 10.1002/recl.19700890613

DO - 10.1002/recl.19700890613

M3 - Article

SN - 0165-0513

VL - 89

SP - 667

EP - 672

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 6

ER -

Formation of open anions from dihydro-oxepin

Abstract

Access to Document

Fingerprint

Cite this