Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols

O.H. Diebolt; C. Müller; C. Cruzeuil; D. Vogt

doi:10.1002/adsc.201100707

Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols

O.H. Diebolt, C. Müller, C. Cruzeuil, D. Vogt

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions.

Original language	English
Pages (from-to)	670-677
Journal	Advanced Synthesis & Catalysis
Volume	354
Issue number	4
DOIs	https://doi.org/10.1002/adsc.201100707
Publication status	Published - 2012

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title = "Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols",

abstract = "Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions.",

author = "O.H. Diebolt and C. M{\"u}ller and C. Cruzeuil and D. Vogt",

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doi = "10.1002/adsc.201100707",

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AU - Diebolt, O.H.

AU - Müller, C.

AU - Cruzeuil, C.

AU - Vogt, D.

PY - 2012

Y1 - 2012

N2 - Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions.

AB - Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions.

U2 - 10.1002/adsc.201100707

DO - 10.1002/adsc.201100707

M3 - Article

SN - 1615-4150

VL - 354

SP - 670

EP - 677

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

IS - 4

ER -

Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols

Abstract

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